Abstract
The development of efficient catalytic methods to cleave the relatively unreactive C-O bonds of ethers remains an important challenge in catalysis. Building on our group's recent work, we report the dehydroaryloxylation of aryl alkyl ethers using pincer iridium catalysts. This method represents a rare fully atom-economical method for ether C-O bond cleavage.
| Original language | English |
|---|---|
| Pages (from-to) | 10160-10163 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 53 |
| Issue number | 38 |
| DOIs | |
| Publication status | Published - Sep 15 2014 |
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Keywords
- C-H activation
- C-O cleavage
- ethers
- iridium
- pincer ligands
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Medicine(all)
Cite this
Catalytic cleavage of ether C-O bonds by pincer iridium complexes. / Haibach, Michael C.; Lease, Nicholas; Goldman, Alan S.
In: Angewandte Chemie - International Edition, Vol. 53, No. 38, 15.09.2014, p. 10160-10163.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Catalytic cleavage of ether C-O bonds by pincer iridium complexes
AU - Haibach, Michael C.
AU - Lease, Nicholas
AU - Goldman, Alan S
PY - 2014/9/15
Y1 - 2014/9/15
N2 - The development of efficient catalytic methods to cleave the relatively unreactive C-O bonds of ethers remains an important challenge in catalysis. Building on our group's recent work, we report the dehydroaryloxylation of aryl alkyl ethers using pincer iridium catalysts. This method represents a rare fully atom-economical method for ether C-O bond cleavage.
AB - The development of efficient catalytic methods to cleave the relatively unreactive C-O bonds of ethers remains an important challenge in catalysis. Building on our group's recent work, we report the dehydroaryloxylation of aryl alkyl ethers using pincer iridium catalysts. This method represents a rare fully atom-economical method for ether C-O bond cleavage.
KW - C-H activation
KW - C-O cleavage
KW - ethers
KW - iridium
KW - pincer ligands
UR - http://www.scopus.com/inward/record.url?scp=84924270243&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84924270243&partnerID=8YFLogxK
U2 - 10.1002/anie.201402576
DO - 10.1002/anie.201402576
M3 - Article
C2 - 25060043
AN - SCOPUS:84924270243
VL - 53
SP - 10160
EP - 10163
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 38
ER -