Catalytic cleavage of ether C-O bonds by pincer iridium complexes

Michael C. Haibach; Nicholas Lease; Alan S. Goldman

doi:10.1002/anie.201402576

Catalytic cleavage of ether C-O bonds by pincer iridium complexes

Michael C. Haibach, Nicholas Lease, Alan S. Goldman

Rutgers University

Research output: Contribution to journal › Article › peer-review

57 Citations (Scopus)

Abstract

The development of efficient catalytic methods to cleave the relatively unreactive C-O bonds of ethers remains an important challenge in catalysis. Building on our group's recent work, we report the dehydroaryloxylation of aryl alkyl ethers using pincer iridium catalysts. This method represents a rare fully atom-economical method for ether C-O bond cleavage.

Original language	English
Pages (from-to)	10160-10163
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	38
DOIs	https://doi.org/10.1002/anie.201402576
Publication status	Published - Sep 15 2014

Keywords

C-H activation
C-O cleavage
ethers
iridium
pincer ligands

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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KW - pincer ligands

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