Abstract
An overview is given of experiments suitable for advanced undergraduates that will introduce them to the preparation and characterization of a bioinorganic model complex. Techniques and concepts emphasized include inorganic synthesis, UV-visible spectroscopy, titrations, heterogeneous catalytic reaction mechanisms, oxidation-reduction reactions, and kinetic and isotope effects. For demonstration purposes, the active site of water oxidation in photosystem II (PSII), the oxygen-evolving complex (OEC), is chosen as a biological metal cluster of interest.
| Original language | English |
|---|---|
| Pages (from-to) | 791-794 |
| Number of pages | 4 |
| Journal | Journal of Chemical Education |
| Volume | 82 |
| Issue number | 5 |
| Publication status | Published - May 2005 |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
- Education
Cite this
Catalytic oxygen evolution by a bioinorganic model of the photosystem II oxygen-evolving complex. / Howard, Derrick L.; Tinoco, Arthur D.; Brudvig, Gary W; Vrettos, John S.; Allen, Bertha Connie.
In: Journal of Chemical Education, Vol. 82, No. 5, 05.2005, p. 791-794.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Catalytic oxygen evolution by a bioinorganic model of the photosystem II oxygen-evolving complex
AU - Howard, Derrick L.
AU - Tinoco, Arthur D.
AU - Brudvig, Gary W
AU - Vrettos, John S.
AU - Allen, Bertha Connie
PY - 2005/5
Y1 - 2005/5
N2 - An overview is given of experiments suitable for advanced undergraduates that will introduce them to the preparation and characterization of a bioinorganic model complex. Techniques and concepts emphasized include inorganic synthesis, UV-visible spectroscopy, titrations, heterogeneous catalytic reaction mechanisms, oxidation-reduction reactions, and kinetic and isotope effects. For demonstration purposes, the active site of water oxidation in photosystem II (PSII), the oxygen-evolving complex (OEC), is chosen as a biological metal cluster of interest.
AB - An overview is given of experiments suitable for advanced undergraduates that will introduce them to the preparation and characterization of a bioinorganic model complex. Techniques and concepts emphasized include inorganic synthesis, UV-visible spectroscopy, titrations, heterogeneous catalytic reaction mechanisms, oxidation-reduction reactions, and kinetic and isotope effects. For demonstration purposes, the active site of water oxidation in photosystem II (PSII), the oxygen-evolving complex (OEC), is chosen as a biological metal cluster of interest.
UR - http://www.scopus.com/inward/record.url?scp=18144391908&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=18144391908&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:18144391908
VL - 82
SP - 791
EP - 794
JO - Journal of Chemical Education
JF - Journal of Chemical Education
SN - 0021-9584
IS - 5
ER -