Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

Ritu Ahuja; Sabuj Kundu; Alan S. Goldman; Maurice Brookhart; Brian C. Vicente; Susannah L. Scott

doi:10.1039/b712197k

Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

Ritu Ahuja, Sabuj Kundu, Alan S. Goldman, Maurice Brookhart, Brian C. Vicente, Susannah L. Scott

Rutgers University

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Tandem dehydrogenation-olefin-metathesis catalyst systems, comprising a pincer-ligated iridium-based alkane dehydrogenation catalyst and a molybdenum-based olefin-metathesis catalyst, are reported to effect the metathesis-cyclooligomerization of cyclooctane and cyclodecane to give cycloalkanes with various carbon numbers, predominantly multiples of the substrate carbon number, and polymers.

Original language	English
Pages (from-to)	253-255
Number of pages	3
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/b712197k
Publication status	Published - Jan 1 2008

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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AU - Kundu, Sabuj

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AU - Brookhart, Maurice

AU - Vicente, Brian C.

AU - Scott, Susannah L.

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Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

Abstract

ASJC Scopus subject areas

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