Abstract
Tandem dehydrogenation-olefin-metathesis catalyst systems, comprising a pincer-ligated iridium-based alkane dehydrogenation catalyst and a molybdenum-based olefin-metathesis catalyst, are reported to effect the metathesis-cyclooligomerization of cyclooctane and cyclodecane to give cycloalkanes with various carbon numbers, predominantly multiples of the substrate carbon number, and polymers.
| Original language | English |
|---|---|
| Pages (from-to) | 253-255 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 2008 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes. / Ahuja, Ritu; Kundu, Sabuj; Goldman, Alan S; Brookhart, Maurice; Vicente, Brian C.; Scott, Susannah L.
In: Chemical Communications, No. 2, 2008, p. 253-255.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes
AU - Ahuja, Ritu
AU - Kundu, Sabuj
AU - Goldman, Alan S
AU - Brookhart, Maurice
AU - Vicente, Brian C.
AU - Scott, Susannah L.
PY - 2008
Y1 - 2008
N2 - Tandem dehydrogenation-olefin-metathesis catalyst systems, comprising a pincer-ligated iridium-based alkane dehydrogenation catalyst and a molybdenum-based olefin-metathesis catalyst, are reported to effect the metathesis-cyclooligomerization of cyclooctane and cyclodecane to give cycloalkanes with various carbon numbers, predominantly multiples of the substrate carbon number, and polymers.
AB - Tandem dehydrogenation-olefin-metathesis catalyst systems, comprising a pincer-ligated iridium-based alkane dehydrogenation catalyst and a molybdenum-based olefin-metathesis catalyst, are reported to effect the metathesis-cyclooligomerization of cyclooctane and cyclodecane to give cycloalkanes with various carbon numbers, predominantly multiples of the substrate carbon number, and polymers.
UR - http://www.scopus.com/inward/record.url?scp=37349072053&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37349072053&partnerID=8YFLogxK
U2 - 10.1039/b712197k
DO - 10.1039/b712197k
M3 - Article
AN - SCOPUS:37349072053
SP - 253
EP - 255
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 2
ER -