Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

Ritu Ahuja; Sabuj Kundu; Alan S. Goldman; Maurice Brookhart; Brian C. Vicente; Susannah L. Scott

doi:10.1039/b712197k

Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes

Ritu Ahuja, Sabuj Kundu, Alan S. Goldman, Maurice Brookhart, Brian C. Vicente, Susannah L. Scott

Rutgers University

Research output: Contribution to journal › Article

57 Citations (Scopus)

Abstract

Tandem dehydrogenation-olefin-metathesis catalyst systems, comprising a pincer-ligated iridium-based alkane dehydrogenation catalyst and a molybdenum-based olefin-metathesis catalyst, are reported to effect the metathesis-cyclooligomerization of cyclooctane and cyclodecane to give cycloalkanes with various carbon numbers, predominantly multiples of the substrate carbon number, and polymers.

Original language	English
Pages (from-to)	253-255
Number of pages	3
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/b712197k
Publication status	Published - Jan 1 2008

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Ahuja, R., Kundu, S., Goldman, A. S., Brookhart, M., Vicente, B. C., & Scott, S. L. (2008). Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes. Chemical Communications, (2), 253-255. https://doi.org/10.1039/b712197k

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10.1039/b712197k