Catalytic selective cleavage of a strong C-C single bond by rhodium in solution

Research output: Contribution to journalArticle

88 Citations (Scopus)

Abstract

Reaction of [RhCl(C8H14)2]2 with an excess of the diphosphine 1,3-bis(diisopropylphosphinomethylene)mesitylene 1 in dioxane under mild H2 pressure (25 psi) or with an excess of HSi(OEt)3 results in catalytic selective cleavage of a strong C-C single bond.

Original languageEnglish
Pages (from-to)687-688
Number of pages2
JournalChemical Communications
Issue number6
Publication statusPublished - Mar 21 1998

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Rhodium
single bond
mesitylene
1,4-dioxane

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Catalytic selective cleavage of a strong C-C single bond by rhodium in solution. / Liou, Shyh Yeon; van der Boom, Milko; Milstein, David.

In: Chemical Communications, No. 6, 21.03.1998, p. 687-688.

Research output: Contribution to journalArticle

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