Catalytic solvolytic and hydrolytic degradation of toxic methyl paraoxon with la(catecholate)-functionalized porous organic polymers

Ryan K. Totten, Mitchell H. Weston, Jin Kuen Park, Omar K. Farha, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

51 Citations (Scopus)

Abstract

Two robust catechol-functionalized porous organic polymers (catPOPs) with different Td-directing nodes were synthesized using a cobalt-catalyzed acetylene trimerization (CCAT) strategy. Postsynthesis metallation was readily carried out with La(acac)3 to afford catalytically active La-functionalized catPOPs for the solvolytic and hydrolytic degradation of the toxic organophosphate compound methyl paraoxon, a simulant for nerve agents.

Original languageEnglish
Pages (from-to)1454-1459
Number of pages6
JournalACS Catalysis
Volume3
Issue number7
DOIs
Publication statusPublished - Jul 5 2013

Fingerprint

Organic polymers
Poisons
Degradation
Acetylene
Organophosphates
Cobalt
catechol
methylparaoxon
Nerve Agents

Keywords

  • catalysis
  • catechol
  • lanthanum
  • organophosphates
  • porous organic polymers

ASJC Scopus subject areas

  • Catalysis

Cite this

Catalytic solvolytic and hydrolytic degradation of toxic methyl paraoxon with la(catecholate)-functionalized porous organic polymers. / Totten, Ryan K.; Weston, Mitchell H.; Park, Jin Kuen; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: ACS Catalysis, Vol. 3, No. 7, 05.07.2013, p. 1454-1459.

Research output: Contribution to journalArticle

Totten, Ryan K. ; Weston, Mitchell H. ; Park, Jin Kuen ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / Catalytic solvolytic and hydrolytic degradation of toxic methyl paraoxon with la(catecholate)-functionalized porous organic polymers. In: ACS Catalysis. 2013 ; Vol. 3, No. 7. pp. 1454-1459.
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