Catalyzed dehydrogenation of amine boranes studied by nmr

John C. Linehan; Nate Szymczak; J. L. Fulton; Yongsheng Chen; Tom Autrey

Catalyzed dehydrogenation of amine boranes studied by nmr

John C. Linehan, Nate Szymczak, J. L. Fulton, Yongsheng Chen, Tom Autrey

Pacific Northwest National Laboratory

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

Rhodium cluster catalyzed dehydrogenation of the amine boranes, cyclohexylamine borane (CAB), t-butylamine borane (tBAB) and dimethylamine borane (DMAB), have been investigated using in situ solution multinuclear techniques. The time evolution of the reaction products was followed. Mechanistic implications of these findings will be discussed.

Original language	English
Title of host publication	Abstracts of Papers - 232nd American Chemical Society Meeting and Exposition
Publication status	Published - Dec 1 2006
Event	232nd American Chemical Society Meeting and Exposition - San Francisco, CA, United States Duration: Sep 10 2006 → Sep 14 2006

Publication series

Name	ACS National Meeting Book of Abstracts
Volume	232
ISSN (Print)	0065-7727

Other

Other	232nd American Chemical Society Meeting and Exposition
Country	United States
City	San Francisco, CA
Period	9/10/06 → 9/14/06

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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title = "Catalyzed dehydrogenation of amine boranes studied by nmr",

abstract = "Rhodium cluster catalyzed dehydrogenation of the amine boranes, cyclohexylamine borane (CAB), t-butylamine borane (tBAB) and dimethylamine borane (DMAB), have been investigated using in situ solution multinuclear techniques. The time evolution of the reaction products was followed. Mechanistic implications of these findings will be discussed.",

author = "Linehan, {John C.} and Nate Szymczak and Fulton, {J. L.} and Yongsheng Chen and Tom Autrey",

year = "2006",

month = dec,

day = "1",

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isbn = "0841274266",

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note = "232nd American Chemical Society Meeting and Exposition ; Conference date: 10-09-2006 Through 14-09-2006",

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AU - Linehan, John C.

AU - Szymczak, Nate

AU - Fulton, J. L.

AU - Chen, Yongsheng

AU - Autrey, Tom

PY - 2006/12/1

Y1 - 2006/12/1

N2 - Rhodium cluster catalyzed dehydrogenation of the amine boranes, cyclohexylamine borane (CAB), t-butylamine borane (tBAB) and dimethylamine borane (DMAB), have been investigated using in situ solution multinuclear techniques. The time evolution of the reaction products was followed. Mechanistic implications of these findings will be discussed.

AB - Rhodium cluster catalyzed dehydrogenation of the amine boranes, cyclohexylamine borane (CAB), t-butylamine borane (tBAB) and dimethylamine borane (DMAB), have been investigated using in situ solution multinuclear techniques. The time evolution of the reaction products was followed. Mechanistic implications of these findings will be discussed.

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M3 - Conference contribution

AN - SCOPUS:34047260267

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SN - 9780841274266

T3 - ACS National Meeting Book of Abstracts

BT - Abstracts of Papers - 232nd American Chemical Society Meeting and Exposition

T2 - 232nd American Chemical Society Meeting and Exposition

Y2 - 10 September 2006 through 14 September 2006

ER -