Cationic Metallocene Polymerization Catalysts. Synthesis and Properities of the First Base‐Free Zirconocene Hydride

Xinmim Yang; Charlotte L. Stern; Tobin J. Marks

doi:10.1002/anie.199213751

Cationic Metallocene Polymerization Catalysts. Synthesis and Properities of the First Base‐Free Zirconocene Hydride

Xinmim Yang, Charlotte L. Stern, Tobin J. Marks

Northwestern University

Research output: Contribution to journal › Article › peer-review

130 Citations (Scopus)

Abstract

High electrophilicity and polymerization activity as well as ion‐pairing effects not based on the bridging hydrogen atoms are the most notable characteristics of the cation in 2, a model compound for Ziegler‐Natta catalysts. This hydrido complex is accessible by hydrogenolysis of 1 or by hydride abstraction from 3. (Formula Presented.)

Original language	English
Pages (from-to)	1375-1377
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	31
Issue number	10
DOIs	https://doi.org/10.1002/anie.199213751
Publication status	Published - Oct 1992

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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abstract = "High electrophilicity and polymerization activity as well as ion‐pairing effects not based on the bridging hydrogen atoms are the most notable characteristics of the cation in 2, a model compound for Ziegler‐Natta catalysts. This hydrido complex is accessible by hydrogenolysis of 1 or by hydride abstraction from 3. (Formula Presented.)",

author = "Xinmim Yang and Stern, {Charlotte L.} and Marks, {Tobin J.}",

year = "1992",

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