Cavity-tailored, self-sorting supramolecular catalytic boxes for selective oxidation

Joong Lee Suk, So Hye Cho, Karen L. Mulfort, David M. Tiede, Joseph T. Hupp, Son Binh T. Nguyen

Research output: Contribution to journalArticlepeer-review

135 Citations (Scopus)

Abstract

Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.

Original languageEnglish
Pages (from-to)16828-16829
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number50
DOIs
Publication statusPublished - Dec 17 2008

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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