Chalcogenide aerogels as sorbents for radioactive iodine

K. S. Subrahmanyam, Debajit Sarma, Christos D. Malliakas, Kyriaki Polychronopoulou, Brian J. Riley, David A. Pierce, Jaehun Chun, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

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Abstract

Iodine (129I and 131I) is one of the radionuclides released in nuclear fuel reprocessing and poses a risk to public safety due to its involvement in human metabolic processes. In order to prevent the release of hazardous radioactive iodine into the environment, its effective capture and sequestration is pivotal. In the context of finding a suitable matrix for capturing radioactive iodine, several sulfidic chalcogels were explored as iodine sorbents including NiMoS4, CoMoS4, Sb4Sn3S12, Zn2Sn2S6, and K0.16CoSx (x = 4-5). All of the chalcogels showed high uptake, reaching up to 225 mass % (2.25 g/g) of the final mass owing to strong chemical and physical iodine-sulfide interactions. Analysis of the iodine-loaded specimens revealed that the iodine chemically reacted with Sb4Sn3S12, Zn2Sn2S6, and K0.16CoSx to form the metal complexes SbI3, SnI4, and, KI, respectively. The NiMoS4 and CoMoS4 chalcogels did not appear to undergo a chemical reaction with iodine since iodide complexes were not observed with these samples. Once heated, the iodine-loaded chalcogels released iodine in the temperature range of 75 to 220 °C, depending on the nature of iodine speciation. In the case of Sb4Sn3S12 and Zn2Sn2S6, iodine release was observed around 150 °C mainly in the form of SnI4 and SbI3, respectively. The NiMoS4, CoMoS4, and K0.16CoSx released elemental iodine at ∼75 °C, which is consistent with physisorption. Preliminary investigations on consolidation of iodine-loaded Zn2Sn2S6 chalcogel with Sb2S3 as a glass forming additive produced glassy material whose iodine content was around 25 mass %.

Original languageEnglish
Pages (from-to)2619-2626
Number of pages8
JournalChemistry of Materials
Volume27
Issue number7
DOIs
Publication statusPublished - Apr 14 2015

Fingerprint

Aerogels
Sorbents
Iodine
Nuclear fuel reprocessing
Physisorption
Coordination Complexes
Iodides
Sulfides
Metal complexes
Radioisotopes
Consolidation

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Subrahmanyam, K. S., Sarma, D., Malliakas, C. D., Polychronopoulou, K., Riley, B. J., Pierce, D. A., ... Kanatzidis, M. G. (2015). Chalcogenide aerogels as sorbents for radioactive iodine. Chemistry of Materials, 27(7), 2619-2626. https://doi.org/10.1021/acs.chemmater.5b00413

Chalcogenide aerogels as sorbents for radioactive iodine. / Subrahmanyam, K. S.; Sarma, Debajit; Malliakas, Christos D.; Polychronopoulou, Kyriaki; Riley, Brian J.; Pierce, David A.; Chun, Jaehun; Kanatzidis, Mercouri G.

In: Chemistry of Materials, Vol. 27, No. 7, 14.04.2015, p. 2619-2626.

Research output: Contribution to journalArticle

Subrahmanyam, KS, Sarma, D, Malliakas, CD, Polychronopoulou, K, Riley, BJ, Pierce, DA, Chun, J & Kanatzidis, MG 2015, 'Chalcogenide aerogels as sorbents for radioactive iodine', Chemistry of Materials, vol. 27, no. 7, pp. 2619-2626. https://doi.org/10.1021/acs.chemmater.5b00413
Subrahmanyam KS, Sarma D, Malliakas CD, Polychronopoulou K, Riley BJ, Pierce DA et al. Chalcogenide aerogels as sorbents for radioactive iodine. Chemistry of Materials. 2015 Apr 14;27(7):2619-2626. https://doi.org/10.1021/acs.chemmater.5b00413
Subrahmanyam, K. S. ; Sarma, Debajit ; Malliakas, Christos D. ; Polychronopoulou, Kyriaki ; Riley, Brian J. ; Pierce, David A. ; Chun, Jaehun ; Kanatzidis, Mercouri G. / Chalcogenide aerogels as sorbents for radioactive iodine. In: Chemistry of Materials. 2015 ; Vol. 27, No. 7. pp. 2619-2626.
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