Chalcogenide chemistry in ionic liquids

Nonlinear optical wave-mixing properties of the double-cubane compound [Sb7S8Br 2](AlCl4)3

Qichun Zhang, In Chung, Joon I. Jang, John B. Ketterson, Mercouri G Kanatzidis

Research output: Contribution to journalArticle

180 Citations (Scopus)

Abstract

(Graph Presented) The new cation [Sb7S8Br 2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl 3 (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

Original languageEnglish
Pages (from-to)9896-9897
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number29
DOIs
Publication statusPublished - Jul 29 2009

Fingerprint

Ionic Liquids
Ionic liquids
Cations
Salts
Positive ions
Infrared radiation
1-ethyl-3-methylimidazolium

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Chalcogenide chemistry in ionic liquids : Nonlinear optical wave-mixing properties of the double-cubane compound [Sb7S8Br 2](AlCl4)3. / Zhang, Qichun; Chung, In; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G.

In: Journal of the American Chemical Society, Vol. 131, No. 29, 29.07.2009, p. 9896-9897.

Research output: Contribution to journalArticle

@article{91c193f981d64d23a6998e6791a71df8,
title = "Chalcogenide chemistry in ionic liquids: Nonlinear optical wave-mixing properties of the double-cubane compound [Sb7S8Br 2](AlCl4)3",
abstract = "(Graph Presented) The new cation [Sb7S8Br 2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl 3 (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.",
author = "Qichun Zhang and In Chung and Jang, {Joon I.} and Ketterson, {John B.} and Kanatzidis, {Mercouri G}",
year = "2009",
month = "7",
day = "29",
doi = "10.1021/ja903881m",
language = "English",
volume = "131",
pages = "9896--9897",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "29",

}

TY - JOUR

T1 - Chalcogenide chemistry in ionic liquids

T2 - Nonlinear optical wave-mixing properties of the double-cubane compound [Sb7S8Br 2](AlCl4)3

AU - Zhang, Qichun

AU - Chung, In

AU - Jang, Joon I.

AU - Ketterson, John B.

AU - Kanatzidis, Mercouri G

PY - 2009/7/29

Y1 - 2009/7/29

N2 - (Graph Presented) The new cation [Sb7S8Br 2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl 3 (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

AB - (Graph Presented) The new cation [Sb7S8Br 2]3+ has a double-cubane structure and forms as the [AlCl4]- salt from the ionic liquid EMIMBr-AlCl 3 (EMIM = 1-ethyl-3-methylimidazolium) at 165°C. The compound is noncentrosymmetric with space group P212121 and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

UR - http://www.scopus.com/inward/record.url?scp=67651218697&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67651218697&partnerID=8YFLogxK

U2 - 10.1021/ja903881m

DO - 10.1021/ja903881m

M3 - Article

VL - 131

SP - 9896

EP - 9897

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 29

ER -