CHARGE TRANSFER AND THERMO-CHROMIC PHENOMENA IN SOLID POLYELECTROLYTES.

J. S. Moore, Samuel I Stupp

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

This work studied a group of ionenes known as poly(xylyl viologens) (PXV's). The bipyridinium moiety present in the backbone of PXV's is known to exhibit chromatic activity, presumably as a result of charge-transfer complexation. The sensitivity of charge-transfer energy levels is these polymers to structural features and molecular environment is discussed in this paper. Pyridinium ionene polymers used in solid state reflectance studies were synthesized from anhydrous bipyridine and the corresponding dihaloxylene by the Menschutkin reaction. Diffuse reflectance data, x-ray scans, and thermogravimetric data are presented.

Original languageEnglish
Title of host publicationPolymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material
PublisherACS
Pages129-135
Number of pages7
Volume54
ISBN (Print)0841209618
Publication statusPublished - 1986

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Polyelectrolytes
Charge transfer
Polymers
Complexation
Electron energy levels
X rays

ASJC Scopus subject areas

  • Engineering(all)

Cite this

Moore, J. S., & Stupp, S. I. (1986). CHARGE TRANSFER AND THERMO-CHROMIC PHENOMENA IN SOLID POLYELECTROLYTES. In Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material (Vol. 54, pp. 129-135). ACS.

CHARGE TRANSFER AND THERMO-CHROMIC PHENOMENA IN SOLID POLYELECTROLYTES. / Moore, J. S.; Stupp, Samuel I.

Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. Vol. 54 ACS, 1986. p. 129-135.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Moore, JS & Stupp, SI 1986, CHARGE TRANSFER AND THERMO-CHROMIC PHENOMENA IN SOLID POLYELECTROLYTES. in Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. vol. 54, ACS, pp. 129-135.
Moore JS, Stupp SI. CHARGE TRANSFER AND THERMO-CHROMIC PHENOMENA IN SOLID POLYELECTROLYTES. In Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. Vol. 54. ACS. 1986. p. 129-135
Moore, J. S. ; Stupp, Samuel I. / CHARGE TRANSFER AND THERMO-CHROMIC PHENOMENA IN SOLID POLYELECTROLYTES. Polymeric Materials Science and Engineering, Proceedings of the ACS Division of Polymeric Material. Vol. 54 ACS, 1986. pp. 129-135
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