Chemical communication between metal-complex-based monolayers

Tarkeshwar Gupta; Milko E. Van Der Boom

doi:10.1002/anie.200705841

Chemical communication between metal-complex-based monolayers

Tarkeshwar Gupta, Milko E. Van Der Boom

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

Look who's talking : Redox-induced chemical communication between surface-confined osmium(II) and ruthenium(III) polypyridyl complexes in organic solvents has been demonstrated. Fe²⁺ was used as electron carrier (see picture), and the output signal of the monolayer reporter system was read optically with a conventional UV/Vis spectrophotometer in the transmission mode. Electron transfer takes place at surface-solution interfaces. (Figure Presented).

Original language	English
Pages (from-to)	2260-2262
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	12
DOIs	https://doi.org/10.1002/anie.200705841
Publication status	Published - Mar 7 2008

Keywords

Monolayers
Sensors
Surface chemistry
Thin films

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200705841

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