Abstract
Look who's talking : Redox-induced chemical communication between surface-confined osmium(II) and ruthenium(III) polypyridyl complexes in organic solvents has been demonstrated. Fe2+ was used as electron carrier (see picture), and the output signal of the monolayer reporter system was read optically with a conventional UV/Vis spectrophotometer in the transmission mode. Electron transfer takes place at surface-solution interfaces. (Figure Presented).
| Original language | English |
|---|---|
| Pages (from-to) | 2260-2262 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - Mar 7 2008 |
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Keywords
- Monolayers
- Sensors
- Surface chemistry
- Thin films
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Medicine(all)
Cite this
Chemical communication between metal-complex-based monolayers. / Gupta, Tarkeshwar; van der Boom, Milko.
In: Angewandte Chemie - International Edition, Vol. 47, No. 12, 07.03.2008, p. 2260-2262.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chemical communication between metal-complex-based monolayers
AU - Gupta, Tarkeshwar
AU - van der Boom, Milko
PY - 2008/3/7
Y1 - 2008/3/7
N2 - Look who's talking : Redox-induced chemical communication between surface-confined osmium(II) and ruthenium(III) polypyridyl complexes in organic solvents has been demonstrated. Fe2+ was used as electron carrier (see picture), and the output signal of the monolayer reporter system was read optically with a conventional UV/Vis spectrophotometer in the transmission mode. Electron transfer takes place at surface-solution interfaces. (Figure Presented).
AB - Look who's talking : Redox-induced chemical communication between surface-confined osmium(II) and ruthenium(III) polypyridyl complexes in organic solvents has been demonstrated. Fe2+ was used as electron carrier (see picture), and the output signal of the monolayer reporter system was read optically with a conventional UV/Vis spectrophotometer in the transmission mode. Electron transfer takes place at surface-solution interfaces. (Figure Presented).
KW - Monolayers
KW - Sensors
KW - Surface chemistry
KW - Thin films
UR - http://www.scopus.com/inward/record.url?scp=41049110041&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=41049110041&partnerID=8YFLogxK
U2 - 10.1002/anie.200705841
DO - 10.1002/anie.200705841
M3 - Article
C2 - 18273848
AN - SCOPUS:41049110041
VL - 47
SP - 2260
EP - 2262
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 12
ER -