Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes

Tom Autrey, Anna Gutowska, Liyu Li, John Linehan, Maciej Gutowski

Research output: Chapter in Book/Report/Conference proceedingConference contribution

12 Citations (Scopus)

Abstract

The DOE has issued a grand Challenge in hydrogen storage to compliment existing programs on hydrogen production and fuel cell development. In response to this challenge, a program that uses a combination of experimental and computational approaches was initiated to study the potential of NHxBHx (x = 1-4) as chemical hydrogen storage materials for on-board hydrogen storage. The experimental efforts on ammonia-borane [NH3BH3] (AB) were presented. The nanometer diameter pores of mesoporous templates were used to control the selectivity of the hydrogen release pathways from AB and polyammonia-borane. When the AB was coated on the inside of the mesoporous silica template, the template would minimize borazine formation by controlling linear polymer growth and minimizing cyclization.

Original languageEnglish
Title of host publicationACS Division of Fuel Chemistry, Preprints
Volume49
Edition1
Publication statusPublished - Mar 2004

Fingerprint

Hydrogen storage
Nanostructured materials
Ammonia
Hydrogen
Hydrogen fuels
Cyclization
Hydrogen production
Fuel cells
Silica
Polymers

ASJC Scopus subject areas

  • Energy(all)

Cite this

Autrey, T., Gutowska, A., Li, L., Linehan, J., & Gutowski, M. (2004). Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes. In ACS Division of Fuel Chemistry, Preprints (1 ed., Vol. 49)

Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes. / Autrey, Tom; Gutowska, Anna; Li, Liyu; Linehan, John; Gutowski, Maciej.

ACS Division of Fuel Chemistry, Preprints. Vol. 49 1. ed. 2004.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Autrey, T, Gutowska, A, Li, L, Linehan, J & Gutowski, M 2004, Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes. in ACS Division of Fuel Chemistry, Preprints. 1 edn, vol. 49.
Autrey T, Gutowska A, Li L, Linehan J, Gutowski M. Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes. In ACS Division of Fuel Chemistry, Preprints. 1 ed. Vol. 49. 2004
Autrey, Tom ; Gutowska, Anna ; Li, Liyu ; Linehan, John ; Gutowski, Maciej. / Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes. ACS Division of Fuel Chemistry, Preprints. Vol. 49 1. ed. 2004.
@inproceedings{d813b026a4ca44149c85945145c356e6,
title = "Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes",
abstract = "The DOE has issued a grand Challenge in hydrogen storage to compliment existing programs on hydrogen production and fuel cell development. In response to this challenge, a program that uses a combination of experimental and computational approaches was initiated to study the potential of NHxBHx (x = 1-4) as chemical hydrogen storage materials for on-board hydrogen storage. The experimental efforts on ammonia-borane [NH3BH3] (AB) were presented. The nanometer diameter pores of mesoporous templates were used to control the selectivity of the hydrogen release pathways from AB and polyammonia-borane. When the AB was coated on the inside of the mesoporous silica template, the template would minimize borazine formation by controlling linear polymer growth and minimizing cyclization.",
author = "Tom Autrey and Anna Gutowska and Liyu Li and John Linehan and Maciej Gutowski",
year = "2004",
month = "3",
language = "English",
volume = "49",
booktitle = "ACS Division of Fuel Chemistry, Preprints",
edition = "1",

}

TY - GEN

T1 - Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes

AU - Autrey, Tom

AU - Gutowska, Anna

AU - Li, Liyu

AU - Linehan, John

AU - Gutowski, Maciej

PY - 2004/3

Y1 - 2004/3

N2 - The DOE has issued a grand Challenge in hydrogen storage to compliment existing programs on hydrogen production and fuel cell development. In response to this challenge, a program that uses a combination of experimental and computational approaches was initiated to study the potential of NHxBHx (x = 1-4) as chemical hydrogen storage materials for on-board hydrogen storage. The experimental efforts on ammonia-borane [NH3BH3] (AB) were presented. The nanometer diameter pores of mesoporous templates were used to control the selectivity of the hydrogen release pathways from AB and polyammonia-borane. When the AB was coated on the inside of the mesoporous silica template, the template would minimize borazine formation by controlling linear polymer growth and minimizing cyclization.

AB - The DOE has issued a grand Challenge in hydrogen storage to compliment existing programs on hydrogen production and fuel cell development. In response to this challenge, a program that uses a combination of experimental and computational approaches was initiated to study the potential of NHxBHx (x = 1-4) as chemical hydrogen storage materials for on-board hydrogen storage. The experimental efforts on ammonia-borane [NH3BH3] (AB) were presented. The nanometer diameter pores of mesoporous templates were used to control the selectivity of the hydrogen release pathways from AB and polyammonia-borane. When the AB was coated on the inside of the mesoporous silica template, the template would minimize borazine formation by controlling linear polymer growth and minimizing cyclization.

UR - http://www.scopus.com/inward/record.url?scp=2542423146&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2542423146&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:2542423146

VL - 49

BT - ACS Division of Fuel Chemistry, Preprints

ER -