Abstract
The DOE has issued a grand Challenge in hydrogen storage to compliment existing programs on hydrogen production and fuel cell development. In response to this challenge, a program that uses a combination of experimental and computational approaches was initiated to study the potential of NHxBHx (x = 1-4) as chemical hydrogen storage materials for on-board hydrogen storage. The experimental efforts on ammonia-borane [NH3BH3] (AB) were presented. The nanometer diameter pores of mesoporous templates were used to control the selectivity of the hydrogen release pathways from AB and polyammonia-borane. When the AB was coated on the inside of the mesoporous silica template, the template would minimize borazine formation by controlling linear polymer growth and minimizing cyclization.
| Original language | English |
|---|---|
| Title of host publication | ACS Division of Fuel Chemistry, Preprints |
| Volume | 49 |
| Edition | 1 |
| Publication status | Published - Mar 2004 |
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ASJC Scopus subject areas
- Energy(all)
Cite this
Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes. / Autrey, Tom; Gutowska, Anna; Li, Liyu; Linehan, John; Gutowski, Maciej.
ACS Division of Fuel Chemistry, Preprints. Vol. 49 1. ed. 2004.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Chemical hydrogen storage in nano-structured materials. Control of hydrogen release and reactivity from ammonia borane complexes
AU - Autrey, Tom
AU - Gutowska, Anna
AU - Li, Liyu
AU - Linehan, John
AU - Gutowski, Maciej
PY - 2004/3
Y1 - 2004/3
N2 - The DOE has issued a grand Challenge in hydrogen storage to compliment existing programs on hydrogen production and fuel cell development. In response to this challenge, a program that uses a combination of experimental and computational approaches was initiated to study the potential of NHxBHx (x = 1-4) as chemical hydrogen storage materials for on-board hydrogen storage. The experimental efforts on ammonia-borane [NH3BH3] (AB) were presented. The nanometer diameter pores of mesoporous templates were used to control the selectivity of the hydrogen release pathways from AB and polyammonia-borane. When the AB was coated on the inside of the mesoporous silica template, the template would minimize borazine formation by controlling linear polymer growth and minimizing cyclization.
AB - The DOE has issued a grand Challenge in hydrogen storage to compliment existing programs on hydrogen production and fuel cell development. In response to this challenge, a program that uses a combination of experimental and computational approaches was initiated to study the potential of NHxBHx (x = 1-4) as chemical hydrogen storage materials for on-board hydrogen storage. The experimental efforts on ammonia-borane [NH3BH3] (AB) were presented. The nanometer diameter pores of mesoporous templates were used to control the selectivity of the hydrogen release pathways from AB and polyammonia-borane. When the AB was coated on the inside of the mesoporous silica template, the template would minimize borazine formation by controlling linear polymer growth and minimizing cyclization.
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M3 - Conference contribution
VL - 49
BT - ACS Division of Fuel Chemistry, Preprints
ER -