Abstract
The construction of thousands of well-defined, porous, metal-organic framework (MOF) structures, spanning a broad range of topologies and an even broader range of pore sizes and chemical functionalities, has fuelled the exploration of many applications. Accompanying this applied focus has been a recognition of the need to engender MOFs with mechanical, thermal and/or chemical stability. Chemical stability in acidic, basic and neutral aqueous solutions is important. Advances over recent years have made it possible to design MOFs that possess different combinations of mechanical, thermal and chemical stability. Here, we review these advances and the associated design principles and synthesis strategies. We focus on how these advances may render MOFs effective as heterogeneous catalysts, both in chemically harsh condensed phases and in thermally challenging conditions relevant to gas-phase reactions. Finally, we briefly discuss future directions of study for the production of highly stable MOFs.
| Original language | English |
|---|---|
| Article number | 15018 |
| Journal | Nature Reviews Materials |
| Volume | 1 |
| DOIs | |
| Publication status | Published - Feb 9 2016 |
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ASJC Scopus subject areas
- Energy (miscellaneous)
- Biomaterials
- Electronic, Optical and Magnetic Materials
- Materials Chemistry
- Surfaces, Coatings and Films
Cite this
Chemical, thermal and mechanical stabilities of metal-organic frameworks. / Howarth, Ashlee J.; Liu, Yangyang; Li, Peng; Li, Zhanyong; Wang, Timothy C.; Hupp, Joseph T; Farha, Omar K.
In: Nature Reviews Materials, Vol. 1, 15018, 09.02.2016.Research output: Contribution to journal › Review article
}
TY - JOUR
T1 - Chemical, thermal and mechanical stabilities of metal-organic frameworks
AU - Howarth, Ashlee J.
AU - Liu, Yangyang
AU - Li, Peng
AU - Li, Zhanyong
AU - Wang, Timothy C.
AU - Hupp, Joseph T
AU - Farha, Omar K.
PY - 2016/2/9
Y1 - 2016/2/9
N2 - The construction of thousands of well-defined, porous, metal-organic framework (MOF) structures, spanning a broad range of topologies and an even broader range of pore sizes and chemical functionalities, has fuelled the exploration of many applications. Accompanying this applied focus has been a recognition of the need to engender MOFs with mechanical, thermal and/or chemical stability. Chemical stability in acidic, basic and neutral aqueous solutions is important. Advances over recent years have made it possible to design MOFs that possess different combinations of mechanical, thermal and chemical stability. Here, we review these advances and the associated design principles and synthesis strategies. We focus on how these advances may render MOFs effective as heterogeneous catalysts, both in chemically harsh condensed phases and in thermally challenging conditions relevant to gas-phase reactions. Finally, we briefly discuss future directions of study for the production of highly stable MOFs.
AB - The construction of thousands of well-defined, porous, metal-organic framework (MOF) structures, spanning a broad range of topologies and an even broader range of pore sizes and chemical functionalities, has fuelled the exploration of many applications. Accompanying this applied focus has been a recognition of the need to engender MOFs with mechanical, thermal and/or chemical stability. Chemical stability in acidic, basic and neutral aqueous solutions is important. Advances over recent years have made it possible to design MOFs that possess different combinations of mechanical, thermal and chemical stability. Here, we review these advances and the associated design principles and synthesis strategies. We focus on how these advances may render MOFs effective as heterogeneous catalysts, both in chemically harsh condensed phases and in thermally challenging conditions relevant to gas-phase reactions. Finally, we briefly discuss future directions of study for the production of highly stable MOFs.
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U2 - 10.1038/natrevmats.2015.18
DO - 10.1038/natrevmats.2015.18
M3 - Review article
VL - 1
JO - Nature Reviews Materials
JF - Nature Reviews Materials
SN - 2058-8437
M1 - 15018
ER -