Abstract
Two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDCs) and black phosphorus (BP) have beneficial electronic, optical, and physical properties at the few-layer limit. As atomically thin materials, 2D TMDCs and BP are highly sensitive to their environment and chemical modification, resulting in a strong dependence of their properties on substrate effects, intrinsic defects, and extrinsic adsorbates. Furthermore, the integration of 2D semiconductors into electronic and optoelectronic devices introduces unique challenges at metal-semiconductor and dielectric-semiconductor interfaces. Here, we review emerging efforts to understand and exploit chemical effects to influence the properties of 2D TMDCs and BP. In some cases, surface chemistry leads to significant degradation, thus necessitating the development of robust passivation schemes. On the other hand, appropriately designed chemical modification can be used to beneficially tailor electronic properties, such as controlling doping levels and charge carrier concentrations. Overall, chemical methods allow substantial tunability of the properties of 2D TMDCs and BP, thereby enabling significant future opportunities to optimize performance for device applications.
Original language | English |
---|---|
Pages (from-to) | 3900-3917 |
Number of pages | 18 |
Journal | ACS Nano |
Volume | 10 |
Issue number | 4 |
DOIs | |
Publication status | Published - Apr 26 2016 |
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Keywords
- anisotropy
- chemistry
- contacts
- covalent
- electronics
- excitons
- noncovalent
- optoelectronics
ASJC Scopus subject areas
- Engineering(all)
- Materials Science(all)
- Physics and Astronomy(all)
Cite this
Chemically Tailoring Semiconducting Two-Dimensional Transition Metal Dichalcogenides and Black Phosphorus. / Ryder, Christopher R.; Wood, Joshua D.; Wells, Spencer A.; Hersam, Mark C.
In: ACS Nano, Vol. 10, No. 4, 26.04.2016, p. 3900-3917.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chemically Tailoring Semiconducting Two-Dimensional Transition Metal Dichalcogenides and Black Phosphorus
AU - Ryder, Christopher R.
AU - Wood, Joshua D.
AU - Wells, Spencer A.
AU - Hersam, Mark C
PY - 2016/4/26
Y1 - 2016/4/26
N2 - Two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDCs) and black phosphorus (BP) have beneficial electronic, optical, and physical properties at the few-layer limit. As atomically thin materials, 2D TMDCs and BP are highly sensitive to their environment and chemical modification, resulting in a strong dependence of their properties on substrate effects, intrinsic defects, and extrinsic adsorbates. Furthermore, the integration of 2D semiconductors into electronic and optoelectronic devices introduces unique challenges at metal-semiconductor and dielectric-semiconductor interfaces. Here, we review emerging efforts to understand and exploit chemical effects to influence the properties of 2D TMDCs and BP. In some cases, surface chemistry leads to significant degradation, thus necessitating the development of robust passivation schemes. On the other hand, appropriately designed chemical modification can be used to beneficially tailor electronic properties, such as controlling doping levels and charge carrier concentrations. Overall, chemical methods allow substantial tunability of the properties of 2D TMDCs and BP, thereby enabling significant future opportunities to optimize performance for device applications.
AB - Two-dimensional (2D) semiconducting transition metal dichalcogenides (TMDCs) and black phosphorus (BP) have beneficial electronic, optical, and physical properties at the few-layer limit. As atomically thin materials, 2D TMDCs and BP are highly sensitive to their environment and chemical modification, resulting in a strong dependence of their properties on substrate effects, intrinsic defects, and extrinsic adsorbates. Furthermore, the integration of 2D semiconductors into electronic and optoelectronic devices introduces unique challenges at metal-semiconductor and dielectric-semiconductor interfaces. Here, we review emerging efforts to understand and exploit chemical effects to influence the properties of 2D TMDCs and BP. In some cases, surface chemistry leads to significant degradation, thus necessitating the development of robust passivation schemes. On the other hand, appropriately designed chemical modification can be used to beneficially tailor electronic properties, such as controlling doping levels and charge carrier concentrations. Overall, chemical methods allow substantial tunability of the properties of 2D TMDCs and BP, thereby enabling significant future opportunities to optimize performance for device applications.
KW - anisotropy
KW - chemistry
KW - contacts
KW - covalent
KW - electronics
KW - excitons
KW - noncovalent
KW - optoelectronics
UR - http://www.scopus.com/inward/record.url?scp=84968912285&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84968912285&partnerID=8YFLogxK
U2 - 10.1021/acsnano.6b01091
DO - 10.1021/acsnano.6b01091
M3 - Article
AN - SCOPUS:84968912285
VL - 10
SP - 3900
EP - 3917
JO - ACS Nano
JF - ACS Nano
SN - 1936-0851
IS - 4
ER -