Abstract
Energy-efficient solid-state-lighting (SSL) technologies are rapidly developing, but the lack of stable, high-performance rare-earth free phosphors may impede the growth of the SSL market. One possible alternative is organic phosphor materials, but these can suffer from lower quantum yields and thermal instability compared to rare-earth phosphors. However, if luminescent organic chromophores can be built into a rigid metal-organic framework, their quantum yields and thermal stability can be greatly improved. This Forum Article discusses the design of a group of such chromophore-based luminescent metal-organic frameworks with exceptionally high performance and rational control of the important parameters that influence their emission properties, including electronic structures of chromophore, coligands, metal ions, and guest molecules.
| Original language | English |
|---|---|
| Pages (from-to) | 7250-7256 |
| Number of pages | 7 |
| Journal | Inorganic Chemistry |
| Volume | 55 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - Aug 1 2016 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
Cite this
Chromophore-Based Luminescent Metal-Organic Frameworks as Lighting Phosphors. / Lustig, William P.; Wang, Fangming; Teat, Simon J.; Hu, Zhichao; Gong, Qihan; Li, Jing.
In: Inorganic Chemistry, Vol. 55, No. 15, 01.08.2016, p. 7250-7256.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chromophore-Based Luminescent Metal-Organic Frameworks as Lighting Phosphors
AU - Lustig, William P.
AU - Wang, Fangming
AU - Teat, Simon J.
AU - Hu, Zhichao
AU - Gong, Qihan
AU - Li, Jing
PY - 2016/8/1
Y1 - 2016/8/1
N2 - Energy-efficient solid-state-lighting (SSL) technologies are rapidly developing, but the lack of stable, high-performance rare-earth free phosphors may impede the growth of the SSL market. One possible alternative is organic phosphor materials, but these can suffer from lower quantum yields and thermal instability compared to rare-earth phosphors. However, if luminescent organic chromophores can be built into a rigid metal-organic framework, their quantum yields and thermal stability can be greatly improved. This Forum Article discusses the design of a group of such chromophore-based luminescent metal-organic frameworks with exceptionally high performance and rational control of the important parameters that influence their emission properties, including electronic structures of chromophore, coligands, metal ions, and guest molecules.
AB - Energy-efficient solid-state-lighting (SSL) technologies are rapidly developing, but the lack of stable, high-performance rare-earth free phosphors may impede the growth of the SSL market. One possible alternative is organic phosphor materials, but these can suffer from lower quantum yields and thermal instability compared to rare-earth phosphors. However, if luminescent organic chromophores can be built into a rigid metal-organic framework, their quantum yields and thermal stability can be greatly improved. This Forum Article discusses the design of a group of such chromophore-based luminescent metal-organic frameworks with exceptionally high performance and rational control of the important parameters that influence their emission properties, including electronic structures of chromophore, coligands, metal ions, and guest molecules.
UR - http://www.scopus.com/inward/record.url?scp=84980319818&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84980319818&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.6b00897
DO - 10.1021/acs.inorgchem.6b00897
M3 - Article
AN - SCOPUS:84980319818
VL - 55
SP - 7250
EP - 7256
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 15
ER -