Chromophore-immobilized luminescent metal-organic frameworks as potential lighting phosphors and chemical sensors

Fangming Wang, Wei Liu, Simon J. Teat, Feng Xu, Hao Wang, Xinlong Wang, Litao An, Jing Li

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

An organic chromophore H4tcbpe-F was synthesized and immobilized into metal-organic frameworks along with two bipyridine derivatives as co-ligands to generate two strongly luminescent materials [Zn2(tcbpe-F)(4,4′-bpy)·xDMA] (1) and [Zn2(tcbpe-F)(bpee)·xDMA] (2) [4,4′-bpy = 4,4′-bipyridine, bpee = 4,4′-bipyridyl-ethylene, tcbpe-F = 4′,4′′′,4′′′′′,4′′′′′′′-(ethene-1,1,2,2-tetrayl)tetrakis(3-fluoro-[1,1′-biphenyl]-4-carboxylic acid), DMA = N,N-dimethylacetamide]. Compounds 1 and 2 are isoreticular and feature a 2-fold interpenetrated three-dimensional porous structure. Both compounds give green-yellow emission under blue light excitation. Compound 1 has a high internal quantum yield of ∼51% when excited at 455 nm and shows selective luminescence signal change (e.g. emission energy and/or intensity) towards different solvents, including both aromatic and nonaromatic volatile organic species. These properties make it potentially useful as a lighting phosphor and a chemical sensor.

Original languageEnglish
Pages (from-to)10249-10252
Number of pages4
JournalChemical Communications
Volume52
Issue number67
DOIs
Publication statusPublished - Jan 1 2016

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Quantum yield
Dynamic mechanical analysis
Chromophores
Chemical sensors
Carboxylic acids
Phosphors
Luminescence
Ethylene
Lighting
Metals
Ligands
Derivatives
2,2'-Dipyridyl
Carboxylic Acids
F 4
ethylene
dimethylacetamide
diphenyl

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Chromophore-immobilized luminescent metal-organic frameworks as potential lighting phosphors and chemical sensors. / Wang, Fangming; Liu, Wei; Teat, Simon J.; Xu, Feng; Wang, Hao; Wang, Xinlong; An, Litao; Li, Jing.

In: Chemical Communications, Vol. 52, No. 67, 01.01.2016, p. 10249-10252.

Research output: Contribution to journalArticle

Wang, Fangming ; Liu, Wei ; Teat, Simon J. ; Xu, Feng ; Wang, Hao ; Wang, Xinlong ; An, Litao ; Li, Jing. / Chromophore-immobilized luminescent metal-organic frameworks as potential lighting phosphors and chemical sensors. In: Chemical Communications. 2016 ; Vol. 52, No. 67. pp. 10249-10252.
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abstract = "An organic chromophore H4tcbpe-F was synthesized and immobilized into metal-organic frameworks along with two bipyridine derivatives as co-ligands to generate two strongly luminescent materials [Zn2(tcbpe-F)(4,4′-bpy)·xDMA] (1) and [Zn2(tcbpe-F)(bpee)·xDMA] (2) [4,4′-bpy = 4,4′-bipyridine, bpee = 4,4′-bipyridyl-ethylene, tcbpe-F = 4′,4′′′,4′′′′′,4′′′′′′′-(ethene-1,1,2,2-tetrayl)tetrakis(3-fluoro-[1,1′-biphenyl]-4-carboxylic acid), DMA = N,N-dimethylacetamide]. Compounds 1 and 2 are isoreticular and feature a 2-fold interpenetrated three-dimensional porous structure. Both compounds give green-yellow emission under blue light excitation. Compound 1 has a high internal quantum yield of ∼51{\%} when excited at 455 nm and shows selective luminescence signal change (e.g. emission energy and/or intensity) towards different solvents, including both aromatic and nonaromatic volatile organic species. These properties make it potentially useful as a lighting phosphor and a chemical sensor.",
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