Abstract
Let's twist again: A "clean reaction" strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels-Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.
| Original language | English |
|---|---|
| Pages (from-to) | 672-675 |
| Number of pages | 4 |
| Journal | Chemistry - An Asian Journal |
| Volume | 7 |
| Issue number | 4 |
| DOIs | |
| Publication status | Published - Apr 2012 |
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Keywords
- density functional theory
- physical properties
- polycycles
- structure elucidation
- twistacenes
ASJC Scopus subject areas
- Chemistry(all)
Cite this
"clean reaction" strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit. / Xiao, Jinchong; Malliakas, Christos D.; Liu, Yi; Zhou, Feng; Li, Gang; Su, Haibin; Kanatzidis, Mercouri G; Wudl, Fred; Zhang, Qichun.
In: Chemistry - An Asian Journal, Vol. 7, No. 4, 04.2012, p. 672-675.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - "clean reaction" strategy to approach a stable, green heptatwistacene containing a single terminal pyrene unit
AU - Xiao, Jinchong
AU - Malliakas, Christos D.
AU - Liu, Yi
AU - Zhou, Feng
AU - Li, Gang
AU - Su, Haibin
AU - Kanatzidis, Mercouri G
AU - Wudl, Fred
AU - Zhang, Qichun
PY - 2012/4
Y1 - 2012/4
N2 - Let's twist again: A "clean reaction" strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels-Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.
AB - Let's twist again: A "clean reaction" strategy based on thermally eliminating lactam bridges from a soluble acene precursor through a retro-Diels-Alder reaction gives a new, stable, green heptatwistacene (see structure). The molecule has a twist angle of 23.49°, is very stable even in air, and has an optical band gap of 1.82 eV.
KW - density functional theory
KW - physical properties
KW - polycycles
KW - structure elucidation
KW - twistacenes
UR - http://www.scopus.com/inward/record.url?scp=84859339008&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84859339008&partnerID=8YFLogxK
U2 - 10.1002/asia.201100910
DO - 10.1002/asia.201100910
M3 - Article
C2 - 22279039
AN - SCOPUS:84859339008
VL - 7
SP - 672
EP - 675
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
SN - 1861-4728
IS - 4
ER -