Co(ii), a catalyst for selective conversion of phenyl rings to carboxylic acid groups

Shashi Bhushan Sinha, Jesús Campos, Gary W Brudvig, Robert H. Crabtree

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

An inexpensive protocol for the conversion of -C6H4R into -COOH groups using Co(ii)-Oxone mixture as the catalytic system is described. A series of substrates containing substituted and non-substituted phenyl groups could be selectively converted into carboxylic acids. Initial mechanistic data have been provided.

Original languageEnglish
Pages (from-to)49395-49399
Number of pages5
JournalRSC Advances
Volume4
Issue number90
DOIs
Publication statusPublished - 2014

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Carboxylic Acids
Carboxylic acids
Catalysts
Substrates
potassium peroxymonosulfuric acid

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Co(ii), a catalyst for selective conversion of phenyl rings to carboxylic acid groups. / Sinha, Shashi Bhushan; Campos, Jesús; Brudvig, Gary W; Crabtree, Robert H.

In: RSC Advances, Vol. 4, No. 90, 2014, p. 49395-49399.

Research output: Contribution to journalArticle

Sinha, Shashi Bhushan ; Campos, Jesús ; Brudvig, Gary W ; Crabtree, Robert H. / Co(ii), a catalyst for selective conversion of phenyl rings to carboxylic acid groups. In: RSC Advances. 2014 ; Vol. 4, No. 90. pp. 49395-49399.
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