Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Yan Xu; Ashlee J. Howarth; Timur Islamoglu; Cleiser T. Da Silva; Joseph T. Hupp; Omar K. Farha

doi:10.1016/j.inoche.2016.03.002

Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Yan Xu, Ashlee J. Howarth, Timur Islamoglu, Cleiser T. Da Silva, Joseph T. Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N₂ sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.

Original language	English
Pages (from-to)	60-63
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	67
DOIs	https://doi.org/10.1016/j.inoche.2016.03.002
Publication status	Published - May 1 2016

Keywords

Metal-organic framework
Non-catenated
Pillared paddlewheel
Post-synthetic modification
Solvent-assisted linker exchange
Transmetallation

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF. / Xu, Yan; Howarth, Ashlee J.; Islamoglu, Timur; Da Silva, Cleiser T.; Hupp, Joseph T.; Farha, Omar K.

In: Inorganic Chemistry Communications, Vol. 67, 01.05.2016, p. 60-63.

Research output: Contribution to journal › Article › peer-review

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title = "Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF",

abstract = "A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.",

keywords = "Metal-organic framework, Non-catenated, Pillared paddlewheel, Post-synthetic modification, Solvent-assisted linker exchange, Transmetallation",

author = "Yan Xu and Howarth, {Ashlee J.} and Timur Islamoglu and {Da Silva}, {Cleiser T.} and Hupp, {Joseph T.} and Farha, {Omar K.}",

note = "Funding Information: We gratefully acknowledge funding from the U. S. Dept. Of Energy, Office of Science, Basic Energy Sciences Program through grant DE-FG02—08ER15967 . Y.X. acknowledges financial support from the program of China Scholarship Council (No. 201406085036). ",

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doi = "10.1016/j.inoche.2016.03.002",

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AU - Xu, Yan

AU - Howarth, Ashlee J.

AU - Islamoglu, Timur

AU - Da Silva, Cleiser T.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

N1 - Funding Information: We gratefully acknowledge funding from the U. S. Dept. Of Energy, Office of Science, Basic Energy Sciences Program through grant DE-FG02—08ER15967 . Y.X. acknowledges financial support from the program of China Scholarship Council (No. 201406085036).

PY - 2016/5/1

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N2 - A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.

AB - A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.

KW - Metal-organic framework

KW - Non-catenated

KW - Pillared paddlewheel

KW - Post-synthetic modification

KW - Solvent-assisted linker exchange

KW - Transmetallation

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Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Abstract

Keywords

ASJC Scopus subject areas

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