Abstract
A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.
| Original language | English |
|---|---|
| Pages (from-to) | 60-63 |
| Number of pages | 4 |
| Journal | Inorganic Chemistry Communications |
| Volume | 67 |
| DOIs | |
| Publication status | Published - May 1 2016 |
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Keywords
- Metal-organic framework
- Non-catenated
- Pillared paddlewheel
- Post-synthetic modification
- Solvent-assisted linker exchange
- Transmetallation
ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF. / Xu, Yan; Howarth, Ashlee J.; Islamoglu, Timur; Da Silva, Cleiser T.; Hupp, Joseph T; Farha, Omar K.
In: Inorganic Chemistry Communications, Vol. 67, 01.05.2016, p. 60-63.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF
AU - Xu, Yan
AU - Howarth, Ashlee J.
AU - Islamoglu, Timur
AU - Da Silva, Cleiser T.
AU - Hupp, Joseph T
AU - Farha, Omar K.
PY - 2016/5/1
Y1 - 2016/5/1
N2 - A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.
AB - A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.
KW - Metal-organic framework
KW - Non-catenated
KW - Pillared paddlewheel
KW - Post-synthetic modification
KW - Solvent-assisted linker exchange
KW - Transmetallation
UR - http://www.scopus.com/inward/record.url?scp=84962608613&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84962608613&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2016.03.002
DO - 10.1016/j.inoche.2016.03.002
M3 - Article
VL - 67
SP - 60
EP - 63
JO - Inorganic Chemistry Communication
JF - Inorganic Chemistry Communication
SN - 1387-7003
ER -