Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Yan Xu; Ashlee J. Howarth; Timur Islamoglu; Cleiser T. Da Silva; Joseph T Hupp; Omar K. Farha

doi:10.1016/j.inoche.2016.03.002

Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Yan Xu, Ashlee J. Howarth, Timur Islamoglu, Cleiser T. Da Silva, Joseph T Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N₂ sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.

Original language	English
Pages (from-to)	60-63
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	67
DOIs	https://doi.org/10.1016/j.inoche.2016.03.002
Publication status	Published - May 1 2016

Keywords

Metal-organic framework
Non-catenated
Pillared paddlewheel
Post-synthetic modification
Solvent-assisted linker exchange
Transmetallation

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

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Xu, Y., Howarth, A. J., Islamoglu, T., Da Silva, C. T., Hupp, J. T., & Farha, O. K. (2016). Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF. Inorganic Chemistry Communications, 67, 60-63. https://doi.org/10.1016/j.inoche.2016.03.002

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abstract = "A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.",

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AU - Islamoglu, Timur

AU - Da Silva, Cleiser T.

AU - Hupp, Joseph T

AU - Farha, Omar K.

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