Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Yan Xu; Ashlee J. Howarth; Timur Islamoglu; Cleiser T. Da Silva; Joseph T Hupp; Omar K. Farha

doi:10.1016/j.inoche.2016.03.002

Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Yan Xu, Ashlee J. Howarth, Timur Islamoglu, Cleiser T. Da Silva, Joseph T Hupp, Omar K. Farha

Northwestern University

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N₂ sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.

Original language	English
Pages (from-to)	60-63
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	67
DOIs	https://doi.org/10.1016/j.inoche.2016.03.002
Publication status	Published - May 1 2016

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Keywords

Metal-organic framework
Non-catenated
Pillared paddlewheel
Post-synthetic modification
Solvent-assisted linker exchange
Transmetallation

ASJC Scopus subject areas

Inorganic Chemistry
Physical and Theoretical Chemistry
Materials Chemistry

Cite this

Xu, Y., Howarth, A. J., Islamoglu, T., Da Silva, C. T., Hupp, J. T., & Farha, O. K. (2016). Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF. Inorganic Chemistry Communications, 67, 60-63. https://doi.org/10.1016/j.inoche.2016.03.002

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abstract = "A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.",

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AU - Da Silva, Cleiser T.

AU - Hupp, Joseph T

AU - Farha, Omar K.

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10.1016/j.inoche.2016.03.002