Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF

Yan Xu, Ashlee J. Howarth, Timur Islamoglu, Cleiser T. Da Silva, Joseph T Hupp, Omar K. Farha

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

A non-catenated nickel (II) pillared paddlewheel metal-organic framework is synthesized through a combination of solvent-assisted linker exchange and transmetallation. Compared to its isostructural Zn(II) analogue, the nickel (II) pillared paddlewheel metal-organic framework features an enhanced N2 sorption performance. It is notable that the nickel (II)-based metal-organic framework could not (in our hands) be synthesized de novo. The experimental results validate that multiple building-block-replacement (BBR) methods can be utilized to access materials that are challenging to synthesize directly.

Original languageEnglish
Pages (from-to)60-63
Number of pages4
JournalInorganic Chemistry Communications
Volume67
DOIs
Publication statusPublished - May 1 2016

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Nickel
Metals
nickel
metals
sorption
Sorption
analogs

Keywords

  • Metal-organic framework
  • Non-catenated
  • Pillared paddlewheel
  • Post-synthetic modification
  • Solvent-assisted linker exchange
  • Transmetallation

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Combining solvent-assisted linker exchange and transmetallation strategies to obtain a new non-catenated nickel (II) pillared-paddlewheel MOF. / Xu, Yan; Howarth, Ashlee J.; Islamoglu, Timur; Da Silva, Cleiser T.; Hupp, Joseph T; Farha, Omar K.

In: Inorganic Chemistry Communications, Vol. 67, 01.05.2016, p. 60-63.

Research output: Contribution to journalArticle

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AU - Hupp, Joseph T

AU - Farha, Omar K.

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