Abstract
Perovskite solar cells (PSCs) have advanced rapidly with power conversion efficiencies (PCEs) now exceeding 22%. Due to the long diffusion lengths of charge carriers in the photoactive layer, a PSC device architecture comprising an electron- transporting layer (ETL) is essential to optimize charge flow and collection for maximum performance. Here, a novel approach is reported to low temperature, solution-processed ZnO ETLs for PSCs using combustion synthesis. Due to the intrinsic passivation effects, high crystallinity, matched energy levels, ideal surface topography, and good chemical compatibility with the perovskite layer, this combustion-derived ZnO enables PCEs approaching 17–20% for three types of perovskite materials systems with no need for ETL doping or surface functionalization.
| Original language | English |
|---|---|
| Article number | 1900265 |
| Journal | Advanced Functional Materials |
| DOIs | |
| Publication status | Published - Jan 1 2019 |
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Keywords
- combustion synthesize
- electron-transporting layer
- intrinsic passivation
- perovskite solar cell
- zinc oxide
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Combustion Synthesized Zinc Oxide Electron-Transport Layers for Efficient and Stable Perovskite Solar Cells. / Zheng, Ding; Wang, Gang; Huang, Wei; Wang, Binghao; Ke, Weijun; Logsdon, Jenna Leigh; Wang, Hanyu; Wang, Zhi; Zhu, Weigang; Yu, Junsheng; Wasielewski, Michael R; Kanatzidis, Mercouri G; Marks, Tobin J; Facchetti, Antonio.
In: Advanced Functional Materials, 01.01.2019.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Combustion Synthesized Zinc Oxide Electron-Transport Layers for Efficient and Stable Perovskite Solar Cells
AU - Zheng, Ding
AU - Wang, Gang
AU - Huang, Wei
AU - Wang, Binghao
AU - Ke, Weijun
AU - Logsdon, Jenna Leigh
AU - Wang, Hanyu
AU - Wang, Zhi
AU - Zhu, Weigang
AU - Yu, Junsheng
AU - Wasielewski, Michael R
AU - Kanatzidis, Mercouri G
AU - Marks, Tobin J
AU - Facchetti, Antonio
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Perovskite solar cells (PSCs) have advanced rapidly with power conversion efficiencies (PCEs) now exceeding 22%. Due to the long diffusion lengths of charge carriers in the photoactive layer, a PSC device architecture comprising an electron- transporting layer (ETL) is essential to optimize charge flow and collection for maximum performance. Here, a novel approach is reported to low temperature, solution-processed ZnO ETLs for PSCs using combustion synthesis. Due to the intrinsic passivation effects, high crystallinity, matched energy levels, ideal surface topography, and good chemical compatibility with the perovskite layer, this combustion-derived ZnO enables PCEs approaching 17–20% for three types of perovskite materials systems with no need for ETL doping or surface functionalization.
AB - Perovskite solar cells (PSCs) have advanced rapidly with power conversion efficiencies (PCEs) now exceeding 22%. Due to the long diffusion lengths of charge carriers in the photoactive layer, a PSC device architecture comprising an electron- transporting layer (ETL) is essential to optimize charge flow and collection for maximum performance. Here, a novel approach is reported to low temperature, solution-processed ZnO ETLs for PSCs using combustion synthesis. Due to the intrinsic passivation effects, high crystallinity, matched energy levels, ideal surface topography, and good chemical compatibility with the perovskite layer, this combustion-derived ZnO enables PCEs approaching 17–20% for three types of perovskite materials systems with no need for ETL doping or surface functionalization.
KW - combustion synthesize
KW - electron-transporting layer
KW - intrinsic passivation
KW - perovskite solar cell
KW - zinc oxide
UR - http://www.scopus.com/inward/record.url?scp=85062370395&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85062370395&partnerID=8YFLogxK
U2 - 10.1002/adfm.201900265
DO - 10.1002/adfm.201900265
M3 - Article
AN - SCOPUS:85062370395
JO - Advanced Functional Materials
JF - Advanced Functional Materials
SN - 1616-301X
M1 - 1900265
ER -