Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks

Haohan Wu, Qihan Gong, David H. Olson, Jing Li

Research output: Contribution to journalArticle

782 Citations (Scopus)

Abstract

Commensurate adsorption of hydrocarbons and alcohols in microporous metal-organic frameworks (MOF) is studied. Diffusion studies of hydrocarbons in microporous MOF materials represent a new topic in adsorption related research. Transport properties of guest molecules are investigated by measuring their transport diffusivity and surface permeability employing state-of-the-art and high temporal and spatial resolution IR microimaging and interference (IF) microscopy. The normal C2-C4 alcohols is found to exhibit commensurate adsorption in RPM3-Zn near room temperature. RPM4-Zn takes up a significantly less amount of benzene and o-xylene compared to RPM3-Zn. Adsorption of styrene in MIL-47 represents another very interesting case. With a CdC double bond in place of a C double bond C single bond in EB, styrene is longer and more rigid than EB.

Original languageEnglish
Pages (from-to)836-868
Number of pages33
JournalChemical Reviews
Volume112
Issue number2
DOIs
Publication statusPublished - Feb 8 2012

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Hydrocarbons
Metals
Alcohols
Adsorption
Styrene
Benzene
Transport properties
Microscopic examination
Molecules
Temperature

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks. / Wu, Haohan; Gong, Qihan; Olson, David H.; Li, Jing.

In: Chemical Reviews, Vol. 112, No. 2, 08.02.2012, p. 836-868.

Research output: Contribution to journalArticle

Wu, Haohan ; Gong, Qihan ; Olson, David H. ; Li, Jing. / Commensurate adsorption of hydrocarbons and alcohols in microporous metal organic frameworks. In: Chemical Reviews. 2012 ; Vol. 112, No. 2. pp. 836-868.
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