Comparative study of titanium-functionalized UiO-66: Support effect on the oxidation of cyclohexene using hydrogen peroxide

Huong Giang T. Nguyen; Lily Mao; Aaron W. Peters; Cornelius O. Audu; Zachary J. Brown; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1039/c5cy00825e

Comparative study of titanium-functionalized UiO-66: Support effect on the oxidation of cyclohexene using hydrogen peroxide

Huong Giang T. Nguyen, Lily Mao, Aaron W. Peters, Cornelius O. Audu, Zachary J. Brown, Omar K. Farha, Joseph T. Hupp, Sonbinh T. Nguyen

Northwestern University

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

A comparative study of the support effect in three different UiO-66-based MOFs - with Ti^IV supported as part of the node (UiO-66-Ti_ex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) - is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Ti_ex.

Original language	English
Pages (from-to)	4444-4451
Number of pages	8
Journal	Catalysis Science and Technology
Volume	5
Issue number	9
DOIs	https://doi.org/10.1039/c5cy00825e
Publication status	Published - Jun 26 2015

ASJC Scopus subject areas

Catalysis

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Comparative study of titanium-functionalized UiO-66 : Support effect on the oxidation of cyclohexene using hydrogen peroxide. / Nguyen, Huong Giang T.; Mao, Lily; Peters, Aaron W.; Audu, Cornelius O.; Brown, Zachary J.; Farha, Omar K.; Hupp, Joseph T.; Nguyen, Sonbinh T.

In: Catalysis Science and Technology, Vol. 5, No. 9, 26.06.2015, p. 4444-4451.

Research output: Contribution to journal › Article › peer-review

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abstract = "A comparative study of the support effect in three different UiO-66-based MOFs - with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) - is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.",

author = "Nguyen, {Huong Giang T.} and Lily Mao and Peters, {Aaron W.} and Audu, {Cornelius O.} and Brown, {Zachary J.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

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AU - Audu, Cornelius O.

AU - Brown, Zachary J.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

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AB - A comparative study of the support effect in three different UiO-66-based MOFs - with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) - is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.

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Comparative study of titanium-functionalized UiO-66: Support effect on the oxidation of cyclohexene using hydrogen peroxide

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