Abstract
A comparative study of the support effect in three different UiO-66-based MOFs - with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) - is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.
| Original language | English |
|---|---|
| Pages (from-to) | 4444-4451 |
| Number of pages | 8 |
| Journal | Catalysis Science and Technology |
| Volume | 5 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - Jun 26 2015 |
ASJC Scopus subject areas
- Catalysis
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Nguyen, H. G. T., Mao, L., Peters, A. W., Audu, C. O., Brown, Z. J., Farha, O. K., Hupp, J. T., & Nguyen, S. T. (2015). Comparative study of titanium-functionalized UiO-66: Support effect on the oxidation of cyclohexene using hydrogen peroxide. Catalysis Science and Technology, 5(9), 4444-4451. https://doi.org/10.1039/c5cy00825e