Comparative study of titanium-functionalized UiO-66: Support effect on the oxidation of cyclohexene using hydrogen peroxide

Huong Giang T Nguyen, Lily Mao, Aaron W. Peters, Cornelius O. Audu, Zachary J. Brown, Omar K. Farha, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

A comparative study of the support effect in three different UiO-66-based MOFs - with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) - is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.

Original languageEnglish
Pages (from-to)4444-4451
Number of pages8
JournalCatalysis Science and Technology
Volume5
Issue number9
DOIs
Publication statusPublished - Jun 26 2015

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Catalyst selectivity
Titanium
Hydrogen peroxide
Hydrogen Peroxide
Catalyst activity
Oxidation
cyclohexene

ASJC Scopus subject areas

  • Catalysis

Cite this

Nguyen, H. G. T., Mao, L., Peters, A. W., Audu, C. O., Brown, Z. J., Farha, O. K., ... Nguyen, S. T. (2015). Comparative study of titanium-functionalized UiO-66: Support effect on the oxidation of cyclohexene using hydrogen peroxide. Catalysis Science and Technology, 5(9), 4444-4451. https://doi.org/10.1039/c5cy00825e

Comparative study of titanium-functionalized UiO-66 : Support effect on the oxidation of cyclohexene using hydrogen peroxide. / Nguyen, Huong Giang T; Mao, Lily; Peters, Aaron W.; Audu, Cornelius O.; Brown, Zachary J.; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: Catalysis Science and Technology, Vol. 5, No. 9, 26.06.2015, p. 4444-4451.

Research output: Contribution to journalArticle

Nguyen, Huong Giang T ; Mao, Lily ; Peters, Aaron W. ; Audu, Cornelius O. ; Brown, Zachary J. ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / Comparative study of titanium-functionalized UiO-66 : Support effect on the oxidation of cyclohexene using hydrogen peroxide. In: Catalysis Science and Technology. 2015 ; Vol. 5, No. 9. pp. 4444-4451.
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