Abstract
A comparative study of the support effect in three different UiO-66-based MOFs - with TiIV supported as part of the node (UiO-66-Tiex), attached to the node (Ti-UiO-66), and on a catecholate organic linker (UiO-66-Cat-Ti) - is reported. The three MOFs were evaluated for their catalytic activity and selectivity in cyclohexene oxidation. Ti-UiO-66 exhibited greater catalytic turnover numbers than UiO-66-Cat-Ti and UiO-66-Tiex.
Original language | English |
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Pages (from-to) | 4444-4451 |
Number of pages | 8 |
Journal | Catalysis Science and Technology |
Volume | 5 |
Issue number | 9 |
DOIs | |
Publication status | Published - Jun 26 2015 |
ASJC Scopus subject areas
- Catalysis