Comparing intermediate range order for alkyl- vs. ether-substituted cations in ionic liquids

Alessandro Triolo; Olga Russina; Ruggero Caminiti; Hideaki Shirota; Heather Y. Lee; Cherry S. Santos; N. Sanjeeva Murthy; Edward W. Castner

doi:10.1039/c2cc31550e

Comparing intermediate range order for alkyl- vs. ether-substituted cations in ionic liquids

Alessandro Triolo, Olga Russina, Ruggero Caminiti, Hideaki Shirota, Heather Y. Lee, Cherry S. Santos, N. Sanjeeva Murthy, Edward W. Castner

Rutgers University

Research output: Contribution to journal › Article › peer-review

92 Citations (Scopus)

Abstract

X-ray scattering data from four pairs of ionic liquids (ILs) are compared. The alkyl-substituted cations show a first sharp diffraction peak between 3 and 4 nm⁻¹ that is not observed for ILs having cations with ether- or hydroxy-substitutions. These observations indicate a significant difference in the intermediate range order for these liquids.

Original language	English
Pages (from-to)	4959-4961
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	41
DOIs	https://doi.org/10.1039/c2cc31550e
Publication status	Published - Apr 25 2012

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Comparing intermediate range order for alkyl- vs. ether-substituted cations in ionic liquids. / Triolo, Alessandro; Russina, Olga; Caminiti, Ruggero; Shirota, Hideaki; Lee, Heather Y.; Santos, Cherry S.; Murthy, N. Sanjeeva; Castner, Edward W.

In: Chemical Communications, Vol. 48, No. 41, 25.04.2012, p. 4959-4961.

Research output: Contribution to journal › Article › peer-review

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