Comparing intermediate range order for alkyl- vs. Ether-substituted cations in ionic liquids

Alessandro Triolo, Olga Russina, Ruggero Caminiti, Hideaki Shirota, Heather Y. Lee, Cherry S. Santos, N. Sanjeeva Murthy, Ed Castner

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

X-ray scattering data from four pairs of ionic liquids (ILs) are compared. The alkyl-substituted cations show a first sharp diffraction peak between 3 and 4 nm -1 that is not observed for ILs having cations with ether- or hydroxy-substitutions. These observations indicate a significant difference in the intermediate range order for these liquids.

Original languageEnglish
Pages (from-to)4959-4961
Number of pages3
JournalChemical Communications
Volume48
Issue number41
DOIs
Publication statusPublished - Apr 25 2012

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Ionic Liquids
Ionic liquids
Ether
Cations
Ethers
Positive ions
X ray scattering
Substitution reactions
Diffraction
Liquids

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Comparing intermediate range order for alkyl- vs. Ether-substituted cations in ionic liquids. / Triolo, Alessandro; Russina, Olga; Caminiti, Ruggero; Shirota, Hideaki; Lee, Heather Y.; Santos, Cherry S.; Murthy, N. Sanjeeva; Castner, Ed.

In: Chemical Communications, Vol. 48, No. 41, 25.04.2012, p. 4959-4961.

Research output: Contribution to journalArticle

Triolo, A, Russina, O, Caminiti, R, Shirota, H, Lee, HY, Santos, CS, Murthy, NS & Castner, E 2012, 'Comparing intermediate range order for alkyl- vs. Ether-substituted cations in ionic liquids', Chemical Communications, vol. 48, no. 41, pp. 4959-4961. https://doi.org/10.1039/c2cc31550e
Triolo A, Russina O, Caminiti R, Shirota H, Lee HY, Santos CS et al. Comparing intermediate range order for alkyl- vs. Ether-substituted cations in ionic liquids. Chemical Communications. 2012 Apr 25;48(41):4959-4961. https://doi.org/10.1039/c2cc31550e
Triolo, Alessandro ; Russina, Olga ; Caminiti, Ruggero ; Shirota, Hideaki ; Lee, Heather Y. ; Santos, Cherry S. ; Murthy, N. Sanjeeva ; Castner, Ed. / Comparing intermediate range order for alkyl- vs. Ether-substituted cations in ionic liquids. In: Chemical Communications. 2012 ; Vol. 48, No. 41. pp. 4959-4961.
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