Complete Mechanistic Elucidation of Current-Voltage Characteristics of Grain Boundaries in a Proton-Conducting Solid Electrolyte

Chih Yuan S. Chang, Igor Lubomirsky, Sangtae Kim

Research output: Contribution to journalArticle

Abstract

Ionic current in proton-conducting polycrystalline ceramics is often hampered a great deal by the grain boundaries, limiting their prospective applications as solid electrolytes for next-generation solid oxide fuel cells. To elucidate the conduction mechanism at the grain boundaries, we use a linear diffusion model and impedance spectroscopy to report complete current-voltage (I-V) characteristics of the grain boundaries in 0.5 mol % Sr-doped LaNbO 4 . We provide the first experimental evidence of complete annihilation of the space charge-induced proton depletion at the grain boundaries upon applying moderate bias voltages. We also show that it is possible to distinguish between the grain boundary resistance caused by the space charge and other sources by analyzing the I-V characteristics. The analysis is equally valid for other solid ionic conductors such that it can serve as an important tool to guide further optimization of the conductivity of polycrystalline solid electrolytes.

Original languageEnglish
Pages (from-to)4396-4400
Number of pages5
JournalJournal of Physical Chemistry C
Volume123
Issue number7
DOIs
Publication statusPublished - Feb 21 2019

Fingerprint

Solid electrolytes
solid electrolytes
Current voltage characteristics
Protons
Grain boundaries
grain boundaries
conduction
protons
electric potential
Electric space charge
space charge
solid oxide fuel cells
Bias voltage
Solid oxide fuel cells (SOFC)
depletion
conductors
Spectroscopy
impedance
ceramics
conductivity

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

Cite this

Complete Mechanistic Elucidation of Current-Voltage Characteristics of Grain Boundaries in a Proton-Conducting Solid Electrolyte. / Chang, Chih Yuan S.; Lubomirsky, Igor; Kim, Sangtae.

In: Journal of Physical Chemistry C, Vol. 123, No. 7, 21.02.2019, p. 4396-4400.

Research output: Contribution to journalArticle

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