Abstract
The authors report the successful in situ intercalation/ polymerization of aniline in layered V2O5.nH2O xerogels to yield films of a novel, conducting polymer/oxide bronze, a layered, molecular composite. It is demonstrated for the first time that the redox intercalation of aniline results in the conductive protonated form of polyaniline. The intercalation reaction reported using layered V2O5.nH2O xerogels is general. The authors have produced stable free standing films containing a variety of other important conducting polymers such as polypyrrole, polythiophene, and their derivatives. It should be noted that this class of materials can be viewed not only as conducting polymer intercalation compounds but also as bronzes.
| Original language | English |
|---|---|
| Pages (from-to) | 4139-4141 |
| Number of pages | 3 |
| Journal | Journal of the American Chemical Society |
| Volume | 111 |
| Issue number | 11 |
| Publication status | Published - Jan 1 1989 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Conductive polymer bronzes. Intercalated polyaniline in V2O5 xerogels. / Kanatzidis, Mercouri G; Wu, Chun Guey; Marcy, Henry O.; Kannewurf, Carl R.
In: Journal of the American Chemical Society, Vol. 111, No. 11, 01.01.1989, p. 4139-4141.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Conductive polymer bronzes. Intercalated polyaniline in V2O5 xerogels
AU - Kanatzidis, Mercouri G
AU - Wu, Chun Guey
AU - Marcy, Henry O.
AU - Kannewurf, Carl R.
PY - 1989/1/1
Y1 - 1989/1/1
N2 - The authors report the successful in situ intercalation/ polymerization of aniline in layered V2O5.nH2O xerogels to yield films of a novel, conducting polymer/oxide bronze, a layered, molecular composite. It is demonstrated for the first time that the redox intercalation of aniline results in the conductive protonated form of polyaniline. The intercalation reaction reported using layered V2O5.nH2O xerogels is general. The authors have produced stable free standing films containing a variety of other important conducting polymers such as polypyrrole, polythiophene, and their derivatives. It should be noted that this class of materials can be viewed not only as conducting polymer intercalation compounds but also as bronzes.
AB - The authors report the successful in situ intercalation/ polymerization of aniline in layered V2O5.nH2O xerogels to yield films of a novel, conducting polymer/oxide bronze, a layered, molecular composite. It is demonstrated for the first time that the redox intercalation of aniline results in the conductive protonated form of polyaniline. The intercalation reaction reported using layered V2O5.nH2O xerogels is general. The authors have produced stable free standing films containing a variety of other important conducting polymers such as polypyrrole, polythiophene, and their derivatives. It should be noted that this class of materials can be viewed not only as conducting polymer intercalation compounds but also as bronzes.
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UR - http://www.scopus.com/inward/citedby.url?scp=0024656347&partnerID=8YFLogxK
M3 - Article
VL - 111
SP - 4139
EP - 4141
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 11
ER -