Confined plasmons in nanofabricated single silver particle pairs: Experimental observations of strong interparticle interactions

Linda Gunnarsson, Tomas Rindzevicius, Juris Prikulis, Bengt Kasemo, Mikael Käll, Shengli Zou, George C Schatz

Research output: Contribution to journalArticle

421 Citations (Scopus)

Abstract

We report on the optical properties of single isolated silver nanodisks and pairs of disks fabricated by electron beam lithography. By systematically varying the disk size and surface separation and recording elastic scattering spectra in different polarization configurations, we found evidence for extremely strong interparticle interactions. The dipolar surface plasmon resonance for polarization parallel to the dimer axis exhibited a red shift as the interdimer separation was decreased; as expected from previous work, an extremely strong shift was observed. The scattering spectra of single particles and pairs separated by more than one particle radius can be well described by the coupled dipole approximation (CDA), where the particles are approximated as point dipoles using a modified dipole polarizability for oblate spheroids. For smaller particle separations (d <20 nm), the simple dipole model severely underestimates the particle interaction, indicating the importance of multipolar fields and finite-size effects. The discrete dipole approximation (DDA), which is a finite-element method, describes the experimental results well even at d <20 nm, including particles that have metallic bridges.

Original languageEnglish
Pages (from-to)1079-1087
Number of pages9
JournalJournal of Physical Chemistry B
Volume109
Issue number3
DOIs
Publication statusPublished - Jan 27 2005

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Plasmons
plasmons
Silver
silver
dipoles
Polarization
Elastic scattering
Particle interactions
Electron beam lithography
Surface plasmon resonance
multipolar fields
Dimers
size separation
oblate spheroids
Optical properties
Scattering
Finite element method
particle interactions
polarization
approximation

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Cite this

Confined plasmons in nanofabricated single silver particle pairs : Experimental observations of strong interparticle interactions. / Gunnarsson, Linda; Rindzevicius, Tomas; Prikulis, Juris; Kasemo, Bengt; Käll, Mikael; Zou, Shengli; Schatz, George C.

In: Journal of Physical Chemistry B, Vol. 109, No. 3, 27.01.2005, p. 1079-1087.

Research output: Contribution to journalArticle

Gunnarsson, Linda ; Rindzevicius, Tomas ; Prikulis, Juris ; Kasemo, Bengt ; Käll, Mikael ; Zou, Shengli ; Schatz, George C. / Confined plasmons in nanofabricated single silver particle pairs : Experimental observations of strong interparticle interactions. In: Journal of Physical Chemistry B. 2005 ; Vol. 109, No. 3. pp. 1079-1087.
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