Conformational molecular rectifiers

Alessandro Troisi, Mark A. Ratner

Research output: Contribution to journalArticle

111 Citations (Scopus)

Abstract

Unimolecular rectification based on voltage-controlled intramolecular stereochemical modification is suggested and computationally investigated. In sharp contrast to present molecular rectifiers, these conformational molecular rectifiers (CMRs) differ in principle from silicon structures, deriving their large, strongly temperature-dependent rectification from the differing current pathways in two dominant conformations, controlled by the interelectrode applied field. Two sorts of CMRs, one based on contact modulation the other on bridge modulation, are calculated: an ambient rectification ratio of 102 can be approached.

Original languageEnglish
Pages (from-to)591-595
Number of pages5
JournalNano letters
Volume4
Issue number4
DOIs
Publication statusPublished - Apr 1 2004

ASJC Scopus subject areas

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

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