Constrained geometry organolanthanide catalysts. Synthesis, structural characterization, and enhanced aminoalkene hydroamination/cyclization activity

Shun Tian, Victor M. Arredondo, Charlotte L. Stern, Tobin J Marks

Research output: Contribution to journalArticle

177 Citations (Scopus)

Abstract

The synthesis and characterization of a series of Me2Si[(η5-C5Me4)( tBuN)]LnE(TMS)2 complexes is described for Ln = Sm, Nd, Yb, Lu; E = CH, N. As precatalysts for aminoalkene hydroamination/cyclization, they are significantly more active than the corresponding (C5Me5)2LnE(TMS)2 complexes.

Original languageEnglish
Pages (from-to)2568-2570
Number of pages3
JournalOrganometallics
Volume18
Issue number14
Publication statusPublished - Jul 5 1999

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Cyclization
Thermodynamic properties
methylidyne
catalysts
Catalysts
Geometry
synthesis
geometry

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Constrained geometry organolanthanide catalysts. Synthesis, structural characterization, and enhanced aminoalkene hydroamination/cyclization activity. / Tian, Shun; Arredondo, Victor M.; Stern, Charlotte L.; Marks, Tobin J.

In: Organometallics, Vol. 18, No. 14, 05.07.1999, p. 2568-2570.

Research output: Contribution to journalArticle

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