Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity

D. D. Devore, F. J. Timmers, D. L. Hasha, R. K. Rosen, Tobin J Marks, P. A. Deck, C. L. Stern

Research output: Contribution to journal › Article

184 Citations (Scopus)

Abstract

Reduction of (η5:η1-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η5:η1-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.

Original languageEnglish
Pages (from-to)3132-3134
Number of pages3
JournalOrganometallics
Volume14
Issue number7
Publication statusPublished - Jul 1995

Fingerprint

Alkenes
dienes
Titanium
alkenes
Thermodynamic properties
polymerization
titanium
Polymerization
Geometry
geometry

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Devore, D. D., Timmers, F. J., Hasha, D. L., Rosen, R. K., Marks, T. J., Deck, P. A., & Stern, C. L. (1995). Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. Organometallics, 14(7), 3132-3134.

Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. / Devore, D. D.; Timmers, F. J.; Hasha, D. L.; Rosen, R. K.; Marks, Tobin J; Deck, P. A.; Stern, C. L.

In: Organometallics, Vol. 14, No. 7, 07.1995, p. 3132-3134.

Research output: Contribution to journal › Article

Devore, DD, Timmers, FJ, Hasha, DL, Rosen, RK, Marks, TJ, Deck, PA & Stern, CL 1995, 'Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity', Organometallics, vol. 14, no. 7, pp. 3132-3134.
Devore DD, Timmers FJ, Hasha DL, Rosen RK, Marks TJ, Deck PA et al. Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. Organometallics. 1995 Jul;14(7):3132-3134.
Devore, D. D. ; Timmers, F. J. ; Hasha, D. L. ; Rosen, R. K. ; Marks, Tobin J ; Deck, P. A. ; Stern, C. L. / Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. In: Organometallics. 1995 ; Vol. 14, No. 7. pp. 3132-3134.
@article{e61fbbc595a240eea31956c4a26b761a,
title = "Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity",
abstract = "Reduction of (η5:η1-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η5:η1-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.",
author = "Devore, {D. D.} and Timmers, {F. J.} and Hasha, {D. L.} and Rosen, {R. K.} and Marks, {Tobin J} and Deck, {P. A.} and Stern, {C. L.}",
year = "1995",
month = "7",
language = "English",
volume = "14",
pages = "3132--3134",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "7",

}

TY - JOUR

T1 - Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity

AU - Devore, D. D.

AU - Timmers, F. J.

AU - Hasha, D. L.

AU - Rosen, R. K.

AU - Marks, Tobin J

AU - Deck, P. A.

AU - Stern, C. L.

PY - 1995/7

Y1 - 1995/7

N2 - Reduction of (η5:η1-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η5:η1-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.

AB - Reduction of (η5:η1-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η5:η1-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.

UR - http://www.scopus.com/inward/record.url?scp=0029344861&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0029344861&partnerID=8YFLogxK

M3 - Article

VL - 14

SP - 3132

EP - 3134

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 7

ER -

Access to Document