Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity

D. D. Devore, F. J. Timmers, D. L. Hasha, R. K. Rosen, Tobin J Marks, P. A. Deck, C. L. Stern

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184 Citations (Scopus)

Abstract

Reduction of (η51-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η51-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.

Original languageEnglish
Pages (from-to)3132-3134
Number of pages3
JournalOrganometallics
Volume14
Issue number7
Publication statusPublished - Jul 1995

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

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    Devore, D. D., Timmers, F. J., Hasha, D. L., Rosen, R. K., Marks, T. J., Deck, P. A., & Stern, C. L. (1995). Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. Organometallics, 14(7), 3132-3134.