Abstract
Reduction of (η5:η1-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η5:η1-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.
Original language | English |
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Pages (from-to) | 3132-3134 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 14 |
Issue number | 7 |
Publication status | Published - Jul 1995 |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry