Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity

D. D. Devore, F. J. Timmers, D. L. Hasha, R. K. Rosen, Tobin J Marks, P. A. Deck, C. L. Stern

Research output: Contribution to journalArticle

184 Citations (Scopus)

Abstract

Reduction of (η51-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η51-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.

Original languageEnglish
Pages (from-to)3132-3134
Number of pages3
JournalOrganometallics
Volume14
Issue number7
Publication statusPublished - Jul 1995

Fingerprint

Alkenes
dienes
Titanium
alkenes
Thermodynamic properties
polymerization
titanium
Polymerization
Geometry
geometry

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Devore, D. D., Timmers, F. J., Hasha, D. L., Rosen, R. K., Marks, T. J., Deck, P. A., & Stern, C. L. (1995). Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. Organometallics, 14(7), 3132-3134.

Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. / Devore, D. D.; Timmers, F. J.; Hasha, D. L.; Rosen, R. K.; Marks, Tobin J; Deck, P. A.; Stern, C. L.

In: Organometallics, Vol. 14, No. 7, 07.1995, p. 3132-3134.

Research output: Contribution to journalArticle

Devore, DD, Timmers, FJ, Hasha, DL, Rosen, RK, Marks, TJ, Deck, PA & Stern, CL 1995, 'Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity', Organometallics, vol. 14, no. 7, pp. 3132-3134.
Devore, D. D. ; Timmers, F. J. ; Hasha, D. L. ; Rosen, R. K. ; Marks, Tobin J ; Deck, P. A. ; Stern, C. L. / Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. In: Organometallics. 1995 ; Vol. 14, No. 7. pp. 3132-3134.
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