Abstract
Reduction of (η5:η1-C5Me4SiMe2NR)TiCl2 with 'BuLi in the presence of various 1,3-dienes yields (η5:η1-C5Me4SiMe2NR)Ti(diene) complexes. The diene coordination mode (π, formally Ti(II), or metallacyclic, formally Ti(IV)) and the activity for olefin polymerization (which can be very high) are highly sensitive to the identity of R.
| Original language | English |
|---|---|
| Pages (from-to) | 3132-3134 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 14 |
| Issue number | 7 |
| Publication status | Published - Jul 1995 |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
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Devore, D. D., Timmers, F. J., Hasha, D. L., Rosen, R. K., Marks, T. J., Deck, P. A., & Stern, C. L. (1995). Constrained-geometry titanium(II) diene complexes. Structural diversity and olefin polymerization activity. Organometallics, 14(7), 3132-3134.