Abstract
Using a single shaped femtosecond pulse, a molecular wavepacket is both tailored and monitored. Several toluene vibrational levels are excited in a controlled manner, both in amplitude and phase, through a quantum coherently controlled non-resonant Raman process. The entire coherent anti-Stokes Raman spectroscopy (CARS) process, that includes excitation and probing of the Raman-induced wavepacket, is enabled by polarization and phase shaping. We achieve a wavepacket detection sensitive to the modes relative phase and further extend the capabilities of the single-pulse CARS technique.
| Original language | English |
|---|---|
| Pages (from-to) | 163-169 |
| Number of pages | 7 |
| Journal | Chemical Physics |
| Volume | 318 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Nov 15 2005 |
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Keywords
- CARS
- Impulsive Raman scattering
- Quantum coherent control
- Single-pulse-CARS
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Atomic and Molecular Physics, and Optics
Cite this
Control and measurement of a non-resonant Raman wavepacket using a single ultrashort pulse. / Polack, T.; Oron, Dan; Silberberg, Y.
In: Chemical Physics, Vol. 318, No. 1-2, 15.11.2005, p. 163-169.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Control and measurement of a non-resonant Raman wavepacket using a single ultrashort pulse
AU - Polack, T.
AU - Oron, Dan
AU - Silberberg, Y.
PY - 2005/11/15
Y1 - 2005/11/15
N2 - Using a single shaped femtosecond pulse, a molecular wavepacket is both tailored and monitored. Several toluene vibrational levels are excited in a controlled manner, both in amplitude and phase, through a quantum coherently controlled non-resonant Raman process. The entire coherent anti-Stokes Raman spectroscopy (CARS) process, that includes excitation and probing of the Raman-induced wavepacket, is enabled by polarization and phase shaping. We achieve a wavepacket detection sensitive to the modes relative phase and further extend the capabilities of the single-pulse CARS technique.
AB - Using a single shaped femtosecond pulse, a molecular wavepacket is both tailored and monitored. Several toluene vibrational levels are excited in a controlled manner, both in amplitude and phase, through a quantum coherently controlled non-resonant Raman process. The entire coherent anti-Stokes Raman spectroscopy (CARS) process, that includes excitation and probing of the Raman-induced wavepacket, is enabled by polarization and phase shaping. We achieve a wavepacket detection sensitive to the modes relative phase and further extend the capabilities of the single-pulse CARS technique.
KW - CARS
KW - Impulsive Raman scattering
KW - Quantum coherent control
KW - Single-pulse-CARS
UR - http://www.scopus.com/inward/record.url?scp=27744492021&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=27744492021&partnerID=8YFLogxK
U2 - 10.1016/j.chemphys.2005.06.018
DO - 10.1016/j.chemphys.2005.06.018
M3 - Article
VL - 318
SP - 163
EP - 169
JO - Chemical Physics
JF - Chemical Physics
SN - 0301-0104
IS - 1-2
ER -