Abstract
Using a single shaped femtosecond pulse, a molecular wavepacket is both tailored and monitored. Several toluene vibrational levels are excited in a controlled manner, both in amplitude and phase, through a quantum coherently controlled non-resonant Raman process. The entire coherent anti-Stokes Raman spectroscopy (CARS) process, that includes excitation and probing of the Raman-induced wavepacket, is enabled by polarization and phase shaping. We achieve a wavepacket detection sensitive to the modes relative phase and further extend the capabilities of the single-pulse CARS technique.
| Original language | English |
|---|---|
| Pages (from-to) | 163-169 |
| Number of pages | 7 |
| Journal | Chemical Physics |
| Volume | 318 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Nov 15 2005 |
Keywords
- CARS
- Impulsive Raman scattering
- Quantum coherent control
- Single-pulse-CARS
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Polack, T., Oron, D., & Silberberg, Y. (2005). Control and measurement of a non-resonant Raman wavepacket using a single ultrashort pulse. Chemical Physics, 318(1-2), 163-169. https://doi.org/10.1016/j.chemphys.2005.06.018