Control over self-assembly through reversible charging of the aromatic building blocks in photofunctional supramolecular fibers

Jonathan Baram, Elijah Shirman, Netanel Ben-Shitrit, Alona Ustinov, Haim Weissman, Iddo Pinkas, Sharon G. Wolf, Boris Rybtchinski

Research output: Contribution to journalArticle

83 Citations (Scopus)

Abstract

Self-assembling systems, whose structure and function can be reversibly controlled in situ are of primary importance for creating multifunctional supramolecular arrays and mimicking the complexity of natural systems. Herein we report on photofunctional fibers self-assembled from perylene diimide cromophores, in which interactions between aromatic monomers can be attenuated through their reduction to anionic species that causes fiber fission. Oxidation with air restores the fibers. The sequence represents reversible supramolecular depolymerization-polymerization in situ and is accompanied by a reversible switching of photofunction.

Original languageEnglish
Pages (from-to)14966-14967
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number45
DOIs
Publication statusPublished - Nov 12 2008

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Perylene
Polymerization
Self assembly
Air
Fibers
Depolymerization
Monomers
Oxidation

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Control over self-assembly through reversible charging of the aromatic building blocks in photofunctional supramolecular fibers. / Baram, Jonathan; Shirman, Elijah; Ben-Shitrit, Netanel; Ustinov, Alona; Weissman, Haim; Pinkas, Iddo; Wolf, Sharon G.; Rybtchinski, Boris.

In: Journal of the American Chemical Society, Vol. 130, No. 45, 12.11.2008, p. 14966-14967.

Research output: Contribution to journalArticle

Baram, Jonathan ; Shirman, Elijah ; Ben-Shitrit, Netanel ; Ustinov, Alona ; Weissman, Haim ; Pinkas, Iddo ; Wolf, Sharon G. ; Rybtchinski, Boris. / Control over self-assembly through reversible charging of the aromatic building blocks in photofunctional supramolecular fibers. In: Journal of the American Chemical Society. 2008 ; Vol. 130, No. 45. pp. 14966-14967.
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