Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abhishek Anan; Rajyalakshmi Vathyam; Krishna K. Sharma; Tewodros Asefa

doi:10.1007/s10562-008-9595-1

Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abhishek Anan, Rajyalakshmi Vathyam, Krishna K. Sharma, Tewodros Asefa

Rutgers University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either β-nitrostyrene or β-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.

Original language	English
Pages (from-to)	142-148
Number of pages	7
Journal	Catalysis Letters
Volume	126
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-008-9595-1
Publication status	Published - Nov 2008

Keywords

Amine-functionalized mesoporous materials
Henry reaction
Nitroalcohol
Nitroaldol condensation
Nitrostyrene

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1007/s10562-008-9595-1

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Controlled synthesis of the henry reaction products : Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts. / Anan, Abhishek; Vathyam, Rajyalakshmi; Sharma, Krishna K.; Asefa, Tewodros.

In: Catalysis Letters, Vol. 126, No. 1-2, 11.2008, p. 142-148.

Research output: Contribution to journal › Article › peer-review

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abstract = "A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either β-nitrostyrene or β-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.",

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note = "Funding Information: Acknowledgments We gratefully acknowledge the financial support by the US National Science Foundation (NSF), CAREER Grant, NSF CHE-0645348 for this work. We wish to thank Cole Duncan for valuable discussion.",

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Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abstract

Keywords

ASJC Scopus subject areas

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