Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abhishek Anan; Rajyalakshmi Vathyam; Krishna K. Sharma; Teddy Asefa

doi:10.1007/s10562-008-9595-1

Controlled synthesis of the henry reaction products

Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts

Abhishek Anan, Rajyalakshmi Vathyam, Krishna K. Sharma, Teddy Asefa

Rutgers University

Research output: Contribution to journal › Article

30 Citations (Scopus)

Abstract

A synthetic method for controlling the Henry reaction products from nitrostyrene to nitroalcohol in heterogeneous catalysis by a simple change of the catalytic sites in organoamine-functionalized mesoporous catalysts is reported. The synthesis resulted in either β-nitrostyrene or β-nitroalcohol by simple change of the types of amine functional groups in the amine-functionalized mesoporous catalysts from primary amines into secondary or tertiary.

Original language	English
Pages (from-to)	142-148
Number of pages	7
Journal	Catalysis Letters
Volume	126
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-008-9595-1
Publication status	Published - Nov 2008

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Reaction products

Amines

Catalysts

Functional groups

Catalysis

Keywords

Amine-functionalized mesoporous materials
Henry reaction
Nitroalcohol
Nitroaldol condensation
Nitrostyrene

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Anan, A., Vathyam, R., Sharma, K. K., & Asefa, T. (2008). Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts. Catalysis Letters, 126(1-2), 142-148. https://doi.org/10.1007/s10562-008-9595-1

Controlled synthesis of the henry reaction products : Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts. / Anan, Abhishek; Vathyam, Rajyalakshmi; Sharma, Krishna K.; Asefa, Teddy.

In: Catalysis Letters, Vol. 126, No. 1-2, 11.2008, p. 142-148.

Research output: Contribution to journal › Article

Anan, A, Vathyam, R, Sharma, KK & Asefa, T 2008, 'Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts', Catalysis Letters, vol. 126, no. 1-2, pp. 142-148. https://doi.org/10.1007/s10562-008-9595-1

Anan A, Vathyam R, Sharma KK, Asefa T. Controlled synthesis of the henry reaction products: Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts. Catalysis Letters. 2008 Nov;126(1-2):142-148. https://doi.org/10.1007/s10562-008-9595-1

Anan, Abhishek ; Vathyam, Rajyalakshmi ; Sharma, Krishna K. ; Asefa, Teddy. / Controlled synthesis of the henry reaction products : Nitroalcohol versus nitrostyrene by a simple change of amino-groups of aminofunctionalized nanoporous catalysts. In: Catalysis Letters. 2008 ; Vol. 126, No. 1-2. pp. 142-148.

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10.1007/s10562-008-9595-1