Conversion of alcohols to carboxylates using water and base with H 2 liberation

Research output: Chapter in Book/Report/Conference proceedingChapter

2 Citations (Scopus)

Abstract

Production of carboxylic acids from alcohols is an important process for both industry and laboratory. Traditional methods usually require environmentally unfriendly oxidants and generate stoichiometric waste. Recently, methods using O 2 as oxidant, oxidation processes applying stoichiometric hydrogen acceptors and acceptorless dehydrogenative coupling reactions to generate carboxylic acids/carboxylic acid salts have been developed. This chapter reviews the reported results on the generation of carboxylic acids/carboxylates by acceptorless dehydrogenative coupling of alcohols and water. The chapter is according to the types of catalysts used; reaction conditions, product yields, and mechanisms are also discussed.

Original languageEnglish
Title of host publicationTopics in Organometallic Chemistry
PublisherSpringer Verlag
Pages175-192
Number of pages18
DOIs
Publication statusPublished - Jan 1 2019

Publication series

NameTopics in Organometallic Chemistry
Volume63
ISSN (Print)1436-6002

Keywords

  • Alcohols
  • Carboxylic acids
  • Catalysis
  • Dehydrogenation
  • Dihydrogen

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry
  • Inorganic Chemistry

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