Abstract
The coordination complexes of polychalcogenide ligands with metal ions are reviewed. In the past two decades, the chemistry of metal polysulfides has been extensively studied, while a great deal of attention is currently being paid to metal polyselenides and polytellurides. Compounds of metal heavy polychaleogenides are primarily of interest regarding their structure and reactivity, but they also provide potential for being used as soluble precursors to some technologically relevant metal chalcogenides. This article focuses on coordination compounds of metal polyselenides and polytellurides, both homoleptic species and organometallic complexes with heavy polychalcogenide co-ligands, from the synthetic and structural point of view. After giving a comprehensive survey of the compounds known to date according to the periodic table, some applications and an outlook in this research area are discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 509-621 |
| Number of pages | 113 |
| Journal | Coordination Chemistry Reviews |
| Volume | 130 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - 1994 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
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Coordination chemistry of heavy polychalcogenide ligands. / Kanatzidis, Mercouri G; Huang, Song Ping.
In: Coordination Chemistry Reviews, Vol. 130, No. 1-2, 1994, p. 509-621.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Coordination chemistry of heavy polychalcogenide ligands
AU - Kanatzidis, Mercouri G
AU - Huang, Song Ping
PY - 1994
Y1 - 1994
N2 - The coordination complexes of polychalcogenide ligands with metal ions are reviewed. In the past two decades, the chemistry of metal polysulfides has been extensively studied, while a great deal of attention is currently being paid to metal polyselenides and polytellurides. Compounds of metal heavy polychaleogenides are primarily of interest regarding their structure and reactivity, but they also provide potential for being used as soluble precursors to some technologically relevant metal chalcogenides. This article focuses on coordination compounds of metal polyselenides and polytellurides, both homoleptic species and organometallic complexes with heavy polychalcogenide co-ligands, from the synthetic and structural point of view. After giving a comprehensive survey of the compounds known to date according to the periodic table, some applications and an outlook in this research area are discussed.
AB - The coordination complexes of polychalcogenide ligands with metal ions are reviewed. In the past two decades, the chemistry of metal polysulfides has been extensively studied, while a great deal of attention is currently being paid to metal polyselenides and polytellurides. Compounds of metal heavy polychaleogenides are primarily of interest regarding their structure and reactivity, but they also provide potential for being used as soluble precursors to some technologically relevant metal chalcogenides. This article focuses on coordination compounds of metal polyselenides and polytellurides, both homoleptic species and organometallic complexes with heavy polychalcogenide co-ligands, from the synthetic and structural point of view. After giving a comprehensive survey of the compounds known to date according to the periodic table, some applications and an outlook in this research area are discussed.
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UR - http://www.scopus.com/inward/citedby.url?scp=0007358872&partnerID=8YFLogxK
U2 - 10.1016/0010-8545(94)80012-X
DO - 10.1016/0010-8545(94)80012-X
M3 - Article
AN - SCOPUS:0007358872
VL - 130
SP - 509
EP - 621
JO - Coordination Chemistry Reviews
JF - Coordination Chemistry Reviews
SN - 0010-8545
IS - 1-2
ER -