Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO2 Reduction

Chung Wei Kung; Cornelius O. Audu; Aaron W. Peters; Hyunho Noh; Omar K. Farha; Joseph T Hupp

doi:10.1021/acsenergylett.7b00621

Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO₂ Reduction

Chung Wei Kung, Cornelius O. Audu, Aaron W. Peters, Hyunho Noh, Omar K. Farha, Joseph T Hupp

Northwestern University

Research output: Contribution to journal › Article

20 Citations (Scopus)

Abstract

Copper nanoparticles are embedded into a solvothermally grown thin film of a zirconium metal-organic framework (MOF), NU-1000, by installing single-site Cu(II) into the NU-1000 thin film via solvothermal deposition in MOFs (SIM) followed by electrochemical reduction of Cu(II) to metallic Cu. The obtained Cu nanoparticles are electrochemically addressable and exhibit promising electrocatalytic activity for CO₂ reduction in an aqueous electrolyte.

Original language	English
Pages (from-to)	2394-2401
Number of pages	8
Journal	ACS Energy Letters
Volume	2
Issue number	10
DOIs	https://doi.org/10.1021/acsenergylett.7b00621
Publication status	Published - Oct 13 2017

Fingerprint

Copper

Metals

Nanoparticles

Thin films

Zirconium

Electrolytes

ASJC Scopus subject areas

Chemistry (miscellaneous)
Energy Engineering and Power Technology
Fuel Technology
Renewable Energy, Sustainability and the Environment
Materials Chemistry

Cite this

Kung, C. W., Audu, C. O., Peters, A. W., Noh, H., Farha, O. K., & Hupp, J. T. (2017). Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO₂ Reduction. ACS Energy Letters, 2(10), 2394-2401. https://doi.org/10.1021/acsenergylett.7b00621

Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO₂ Reduction. / Kung, Chung Wei; Audu, Cornelius O.; Peters, Aaron W.; Noh, Hyunho; Farha, Omar K.; Hupp, Joseph T.

In: ACS Energy Letters, Vol. 2, No. 10, 13.10.2017, p. 2394-2401.

Research output: Contribution to journal › Article

Kung, CW, Audu, CO, Peters, AW, Noh, H, Farha, OK & Hupp, JT 2017, 'Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO₂ Reduction', ACS Energy Letters, vol. 2, no. 10, pp. 2394-2401. https://doi.org/10.1021/acsenergylett.7b00621

Kung CW, Audu CO, Peters AW, Noh H, Farha OK, Hupp JT. Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO₂ Reduction. ACS Energy Letters. 2017 Oct 13;2(10):2394-2401. https://doi.org/10.1021/acsenergylett.7b00621

Kung, Chung Wei ; Audu, Cornelius O. ; Peters, Aaron W. ; Noh, Hyunho ; Farha, Omar K. ; Hupp, Joseph T. / Copper Nanoparticles Installed in Metal-Organic Framework Thin Films are Electrocatalytically Competent for CO₂ Reduction. In: ACS Energy Letters. 2017 ; Vol. 2, No. 10. pp. 2394-2401.

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Access to Document

10.1021/acsenergylett.7b00621