CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation

Amit Kumar, Prosenjit Daw, Noel Angel Espinosa-Jalapa, Gregory Leitus, Linda J.W. Shimon, Yehoshoa Ben-David, David Milstein

Research output: Contribution to journalArticle

Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal-ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

Original languageEnglish
Pages (from-to)14580-14584
Number of pages5
JournalDalton Transactions
Volume48
Issue number39
DOIs
Publication statusPublished - Jan 1 2019

Fingerprint

Manganese
Metals
Chemical activation
Ligands
Aromatization
Hydrogenation
Catalyst activity

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Kumar, A., Daw, P., Espinosa-Jalapa, N. A., Leitus, G., Shimon, L. J. W., Ben-David, Y., & Milstein, D. (2019). CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation. Dalton Transactions, 48(39), 14580-14584. https://doi.org/10.1039/c9dt03088c

CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation. / Kumar, Amit; Daw, Prosenjit; Espinosa-Jalapa, Noel Angel; Leitus, Gregory; Shimon, Linda J.W.; Ben-David, Yehoshoa; Milstein, David.

In: Dalton Transactions, Vol. 48, No. 39, 01.01.2019, p. 14580-14584.

Research output: Contribution to journalArticle

Kumar, A, Daw, P, Espinosa-Jalapa, NA, Leitus, G, Shimon, LJW, Ben-David, Y & Milstein, D 2019, 'CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation', Dalton Transactions, vol. 48, no. 39, pp. 14580-14584. https://doi.org/10.1039/c9dt03088c
Kumar A, Daw P, Espinosa-Jalapa NA, Leitus G, Shimon LJW, Ben-David Y et al. CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation. Dalton Transactions. 2019 Jan 1;48(39):14580-14584. https://doi.org/10.1039/c9dt03088c
Kumar, Amit ; Daw, Prosenjit ; Espinosa-Jalapa, Noel Angel ; Leitus, Gregory ; Shimon, Linda J.W. ; Ben-David, Yehoshoa ; Milstein, David. / CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation. In: Dalton Transactions. 2019 ; Vol. 48, No. 39. pp. 14580-14584.
@article{61a67fd79d9847829e8efb863659bd94,
title = "CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation",
abstract = "We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal-ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.",
author = "Amit Kumar and Prosenjit Daw and Espinosa-Jalapa, {Noel Angel} and Gregory Leitus and Shimon, {Linda J.W.} and Yehoshoa Ben-David and David Milstein",
year = "2019",
month = "1",
day = "1",
doi = "10.1039/c9dt03088c",
language = "English",
volume = "48",
pages = "14580--14584",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "39",

}

TY - JOUR

T1 - CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation

AU - Kumar, Amit

AU - Daw, Prosenjit

AU - Espinosa-Jalapa, Noel Angel

AU - Leitus, Gregory

AU - Shimon, Linda J.W.

AU - Ben-David, Yehoshoa

AU - Milstein, David

PY - 2019/1/1

Y1 - 2019/1/1

N2 - We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal-ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

AB - We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal-ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

UR - http://www.scopus.com/inward/record.url?scp=85072992602&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85072992602&partnerID=8YFLogxK

U2 - 10.1039/c9dt03088c

DO - 10.1039/c9dt03088c

M3 - Article

C2 - 31517365

AN - SCOPUS:85072992602

VL - 48

SP - 14580

EP - 14584

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 39

ER -