CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation

Amit Kumar, Prosenjit Daw, Noel Angel Espinosa-Jalapa, Gregory Leitus, Linda J.W. Shimon, Yehoshoa Ben-David, David Milstein

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Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal-ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

Original languageEnglish
Pages (from-to)14580-14584
Number of pages5
JournalDalton Transactions
Volume48
Issue number39
DOIs
Publication statusPublished - Jan 1 2019

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ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Kumar, A., Daw, P., Espinosa-Jalapa, N. A., Leitus, G., Shimon, L. J. W., Ben-David, Y., & Milstein, D. (2019). CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation. Dalton Transactions, 48(39), 14580-14584. https://doi.org/10.1039/c9dt03088c