Covalent surface modification of a metal-organic framework

Selective surface engineering via CuI-catalyzed Huisgen cycloaddition

Tendai Gadzikwa, Guang Lu, Charlotte L. Stern, Scott R. Wilson, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

119 Citations (Scopus)

Abstract

A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.

Original languageEnglish
Pages (from-to)5493-5495
Number of pages3
JournalChemical Communications
Issue number43
DOIs
Publication statusPublished - 2008

Fingerprint

Bearings (structural)
Alkynes
Cycloaddition
Acetylene
Surface treatment
Demonstrations
Metals
Ligands
Molecules

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

Covalent surface modification of a metal-organic framework : Selective surface engineering via CuI-catalyzed Huisgen cycloaddition. / Gadzikwa, Tendai; Lu, Guang; Stern, Charlotte L.; Wilson, Scott R.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: Chemical Communications, No. 43, 2008, p. 5493-5495.

Research output: Contribution to journalArticle

Gadzikwa, Tendai ; Lu, Guang ; Stern, Charlotte L. ; Wilson, Scott R. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / Covalent surface modification of a metal-organic framework : Selective surface engineering via CuI-catalyzed Huisgen cycloaddition. In: Chemical Communications. 2008 ; No. 43. pp. 5493-5495.
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