Covalent surface modification of a metal-organic framework: Selective surface engineering via CuI-catalyzed Huisgen cycloaddition

Tendai Gadzikwa; Guang Lu; Charlotte L. Stern; Scott R. Wilson; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1039/b805101a

Covalent surface modification of a metal-organic framework: Selective surface engineering via Cu^I-catalyzed Huisgen cycloaddition

Tendai Gadzikwa, Guang Lu, Charlotte L. Stern, Scott R. Wilson, Joseph T. Hupp, Sonbinh T. Nguyen

Northwestern University

Research output: Contribution to journal › Article

122 Citations (Scopus)

Abstract

A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.

Original language	English
Pages (from-to)	5493-5495
Number of pages	3
Journal	Chemical Communications
Issue number	43
DOIs	https://doi.org/10.1039/b805101a
Publication status	Published - 2008

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Gadzikwa, T., Lu, G., Stern, C. L., Wilson, S. R., Hupp, J. T., & Nguyen, S. T. (2008). Covalent surface modification of a metal-organic framework: Selective surface engineering via Cu^I-catalyzed Huisgen cycloaddition. Chemical Communications, (43), 5493-5495. https://doi.org/10.1039/b805101a

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abstract = "A Zn-cornered, mixed-ligand, metal-organic framework (MOF) bearing TMS-protected acetylenes has been constructed and its surface decorated with organic molecules via'click chemistry', in a demonstration of selective post-synthesis functionalization.",

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Access to Document

10.1039/b805101a