Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang; Alexander J. Norquist; Jason Pless; Charlotte L. Stern; Douglas A. Vander Griend; Kenneth R Poeppelmeier

doi:10.1016/S0925-8388(02)00178-0

Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang, Alexander J. Norquist, Jason Pless, Charlotte L. Stern, Douglas A. Vander Griend, Kenneth R Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

The solid solution crystals of Mg_1-xFe_xMo_2-xV_xO₇ (0.13≤x≤0.47) grown from MgO-Fe₂O₃-V₂O₅-MoO₃ melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO₇ and MgMo₂O₇. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo₂O₇ and FeVMoO₇.

Original language	English
Pages (from-to)	26-31
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	338
Issue number	1-2 SPEC.
DOIs	https://doi.org/10.1016/S0925-8388(02)00178-0
Publication status	Published - May 16 2002

Keywords

Crystal growth
Metal oxo double bond
Molybdate
Vanadate

ASJC Scopus subject areas

Metals and Alloys

Access to Document

10.1016/S0925-8388(02)00178-0

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Wang, X., Norquist, A. J., Pless, J., Stern, C. L., Vander Griend, D. A., & Poeppelmeier, K. R. (2002). Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds. Journal of Alloys and Compounds, 338(1-2 SPEC.), 26-31. https://doi.org/10.1016/S0925-8388(02)00178-0

Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds. / Wang, Xiandong; Norquist, Alexander J.; Pless, Jason; Stern, Charlotte L.; Vander Griend, Douglas A.; Poeppelmeier, Kenneth R.

In: Journal of Alloys and Compounds, Vol. 338, No. 1-2 SPEC., 16.05.2002, p. 26-31.

Research output: Contribution to journal › Article

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title = "Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds",

abstract = "The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.",

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