TY - JOUR
T1 - Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds
AU - Wang, Xiandong
AU - Norquist, Alexander J.
AU - Pless, Jason
AU - Stern, Charlotte L.
AU - Vander Griend, Douglas A.
AU - Poeppelmeier, Kenneth R.
N1 - Funding Information:
The authors thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation, Solid State Chemistry (DMR-9412971 and DMR-9727516) and made use of the Central Facilities supported by MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Science Center of Northwestern University, and the EMSI program of the NSF and the Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis.
PY - 2002/5/16
Y1 - 2002/5/16
N2 - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.
AB - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.
KW - Crystal growth
KW - Metal oxo double bond
KW - Molybdate
KW - Vanadate
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U2 - 10.1016/S0925-8388(02)00178-0
DO - 10.1016/S0925-8388(02)00178-0
M3 - Article
AN - SCOPUS:0037118121
VL - 338
SP - 26
EP - 31
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
IS - 1-2 SPEC.
ER -