Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang; Alexander J. Norquist; Jason Pless; Charlotte L. Stern; Douglas A. Vander Griend; Kenneth R Poeppelmeier

doi:10.1016/S0925-8388(02)00178-0

Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang, Alexander J. Norquist, Jason Pless, Charlotte L. Stern, Douglas A. Vander Griend, Kenneth R Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article

5 Citations (Scopus)

Abstract

The solid solution crystals of Mg_1-xFe_xMo_2-xV_xO₇ (0.13≤x≤0.47) grown from MgO-Fe₂O₃-V₂O₅-MoO₃ melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO₇ and MgMo₂O₇. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo₂O₇ and FeVMoO₇.

Original language	English
Pages (from-to)	26-31
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	338
Issue number	1-2 SPEC.
DOIs	https://doi.org/10.1016/S0925-8388(02)00178-0
Publication status	Published - May 16 2002

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Crystallization

Crystal growth

Solid solutions

Substitution reactions

Diffraction

Single crystals

X rays

Crystals

molybdenum trioxide

vanadium pentoxide

Keywords

Crystal growth
Metal oxo double bond
Molybdate
Vanadate

ASJC Scopus subject areas

Metals and Alloys

Cite this

Wang, X., Norquist, A. J., Pless, J., Stern, C. L., Vander Griend, D. A., & Poeppelmeier, K. R. (2002). Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds. Journal of Alloys and Compounds, 338(1-2 SPEC.), 26-31. https://doi.org/10.1016/S0925-8388(02)00178-0

Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds. / Wang, Xiandong; Norquist, Alexander J.; Pless, Jason; Stern, Charlotte L.; Vander Griend, Douglas A.; Poeppelmeier, Kenneth R.

In: Journal of Alloys and Compounds, Vol. 338, No. 1-2 SPEC., 16.05.2002, p. 26-31.

Research output: Contribution to journal › Article

Wang, X, Norquist, AJ, Pless, J, Stern, CL, Vander Griend, DA & Poeppelmeier, KR 2002, 'Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds', Journal of Alloys and Compounds, vol. 338, no. 1-2 SPEC., pp. 26-31. https://doi.org/10.1016/S0925-8388(02)00178-0

Wang X, Norquist AJ, Pless J, Stern CL, Vander Griend DA, Poeppelmeier KR. Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds. Journal of Alloys and Compounds. 2002 May 16;338(1-2 SPEC.):26-31. https://doi.org/10.1016/S0925-8388(02)00178-0

Wang, Xiandong ; Norquist, Alexander J. ; Pless, Jason ; Stern, Charlotte L. ; Vander Griend, Douglas A. ; Poeppelmeier, Kenneth R. / Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds. In: Journal of Alloys and Compounds. 2002 ; Vol. 338, No. 1-2 SPEC. pp. 26-31.

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abstract = "The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.",

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AU - Norquist, Alexander J.

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AU - Stern, Charlotte L.

AU - Vander Griend, Douglas A.

AU - Poeppelmeier, Kenneth R

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N2 - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.

AB - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.

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KW - Molybdate

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10.1016/S0925-8388(02)00178-0