Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang; Alexander J. Norquist; Jason Pless; Charlotte L. Stern; Douglas A. Vander Griend; Kenneth R. Poeppelmeier

doi:10.1016/S0925-8388(02)00178-0

Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang, Alexander J. Norquist, Jason Pless, Charlotte L. Stern, Douglas A. Vander Griend, Kenneth R. Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The solid solution crystals of Mg_1-xFe_xMo_2-xV_xO₇ (0.13≤x≤0.47) grown from MgO-Fe₂O₃-V₂O₅-MoO₃ melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO₇ and MgMo₂O₇. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo₂O₇ and FeVMoO₇.

Original language	English
Pages (from-to)	26-31
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	338
Issue number	1-2 SPEC.
DOIs	https://doi.org/10.1016/S0925-8388(02)00178-0
Publication status	Published - May 16 2002

Keywords

Crystal growth
Metal oxo double bond
Molybdate
Vanadate

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0925-8388(02)00178-0

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Crystal growth and co-substitution in (Mg_1-xFe_x)(Mo_2-xV_x)O₇ (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds. / Wang, Xiandong; Norquist, Alexander J.; Pless, Jason; Stern, Charlotte L.; Vander Griend, Douglas A.; Poeppelmeier, Kenneth R.

In: Journal of Alloys and Compounds, Vol. 338, No. 1-2 SPEC., 16.05.2002, p. 26-31.

Research output: Contribution to journal › Article › peer-review

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title = "Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds",

abstract = "The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.",

keywords = "Crystal growth, Metal oxo double bond, Molybdate, Vanadate",

author = "Xiandong Wang and Norquist, {Alexander J.} and Jason Pless and Stern, {Charlotte L.} and {Vander Griend}, {Douglas A.} and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: The authors thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation, Solid State Chemistry (DMR-9412971 and DMR-9727516) and made use of the Central Facilities supported by MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Science Center of Northwestern University, and the EMSI program of the NSF and the Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis. ",

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T1 - Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

AU - Wang, Xiandong

AU - Norquist, Alexander J.

AU - Pless, Jason

AU - Stern, Charlotte L.

AU - Vander Griend, Douglas A.

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: The authors thank Dr. Larry Cirjak and acknowledge a Research Award from BP America. This work was also supported by the National Science Foundation, Solid State Chemistry (DMR-9412971 and DMR-9727516) and made use of the Central Facilities supported by MRSEC program of the National Science Foundation (DMR-0076097) at the Materials Science Center of Northwestern University, and the EMSI program of the NSF and the Department of Energy (CHE-9810378) at the Northwestern University Institute for Environmental Catalysis.

PY - 2002/5/16

Y1 - 2002/5/16

N2 - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.

AB - The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.

KW - Crystal growth

KW - Metal oxo double bond

KW - Molybdate

KW - Vanadate

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