Crystal growth and co-substitution in (Mg1-xFex)(Mo2-xVx)O7 (0.13≤x≤0.47) with (V/Mo)=O oxo double bonds

Xiandong Wang, Alexander J. Norquist, Jason Pless, Charlotte L. Stern, Douglas A. Vander Griend, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The solid solution crystals of Mg1-xFexMo2-xVxO7 (0.13≤x≤0.47) grown from MgO-Fe2O3-V2O5-MoO3 melts were discussed. Its structure was analyzed by x-ray single crystal diffraction and the results were compared with FeVMoO7 and MgMo2O7. It was found that the structure contains (V/Mo)=O oxo double bonds similar to MgMo2O7 and FeVMoO7.

Original languageEnglish
Pages (from-to)26-31
Number of pages6
JournalJournal of Alloys and Compounds
Volume338
Issue number1-2 SPEC.
DOIs
Publication statusPublished - May 16 2002

Keywords

  • Crystal growth
  • Metal oxo double bond
  • Molybdate
  • Vanadate

ASJC Scopus subject areas

  • Metals and Alloys

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