Crystal Growth and Linear and Nonlinear Optical Properties of KIO3·Te(OH)6

Hongping Wu, Hongwei Yu, Weiguo Zhang, Jacqueline Cantwell, Kenneth R Poeppelmeier, Shilie Pan, P. Shiv Halasyamani

Research output: Contribution to journalArticle

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Abstract

A single crystal of the nonlinear optical material KIO3·Te(OH)6 (KTI) with dimensions of 37 × 7 × 5 mm3 was successfully grown at room temperature by slow evaporation. Linear and nonlinear optical measurements were performed on these crystals. Rocking curve measurements indicate that the single crystal is of high quality with a full width at half-maximum (fwhm) of 0.023° (82 arcseconds) from the (010) reflection. Refractive index measurements revealed a birefringence of 0.0545 @ 1064 nm. Through the refractive index measurements and the fitted Sellmeier equations, we determined the Type I and Type II phase-matching wavelength ranges. KTI is Type I (Type II) phase-matchable with a fundamental wavelength range from 674-3266 nm (880-2260 nm). Powder second-harmonic generation (SHG) measurements indicate an SHG intensity of 1.2× KH2PO4 (KDP). SHG coefficients were determined by the Maker fringe method on cut and polished (100) and (010) single crystal wafers. The d31 = 0.24 pm/V and d32 = 0.73 pm/V were determined. Laser damage threshold (LDT) measurements were also performed, which indicates that KTI has an LDT of 731 MW/cm2 at 1064 nm with a 6 ns pulse width.

Original languageEnglish
Pages (from-to)4405-4412
Number of pages8
JournalCrystal Growth and Design
Volume17
Issue number8
DOIs
Publication statusPublished - Aug 2 2017

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Crystallization
Crystal growth
crystal growth
Optical properties
optical properties
Harmonic generation
harmonic generations
laser damage
yield point
Laser damage
Single crystals
single crystals
Refractive index
refractivity
optical materials
Wavelength
phase matching
Phase matching
Optical materials
optical measurement

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Crystal Growth and Linear and Nonlinear Optical Properties of KIO3·Te(OH)6. / Wu, Hongping; Yu, Hongwei; Zhang, Weiguo; Cantwell, Jacqueline; Poeppelmeier, Kenneth R; Pan, Shilie; Halasyamani, P. Shiv.

In: Crystal Growth and Design, Vol. 17, No. 8, 02.08.2017, p. 4405-4412.

Research output: Contribution to journalArticle

Wu, H, Yu, H, Zhang, W, Cantwell, J, Poeppelmeier, KR, Pan, S & Halasyamani, PS 2017, 'Crystal Growth and Linear and Nonlinear Optical Properties of KIO3·Te(OH)6', Crystal Growth and Design, vol. 17, no. 8, pp. 4405-4412. https://doi.org/10.1021/acs.cgd.7b00704
Wu, Hongping ; Yu, Hongwei ; Zhang, Weiguo ; Cantwell, Jacqueline ; Poeppelmeier, Kenneth R ; Pan, Shilie ; Halasyamani, P. Shiv. / Crystal Growth and Linear and Nonlinear Optical Properties of KIO3·Te(OH)6. In: Crystal Growth and Design. 2017 ; Vol. 17, No. 8. pp. 4405-4412.
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