Crystal growth of Ag3 M OxF6-x (M = V, x = 2; M = Mo, x = 3)

Julia M. Chamberlain, Thomas A. Albrecht, Julien Lesage, Frédéric Sauvage, Charlotte L. Stern, Kenneth R. Poeppelmeier

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

Understanding the complex relationship between synthesis conditions, in particular temperature and composition, led to single crystals of the cryolite type phases Ag3MoO3F3 and Ag3VO 2F4. These crystals form in a reversible thermodynamic process from dissolved species when the solution is heated. Single crystal structural data reveal the Mo6+ cation distorted toward facially coordinated oxides for Ag3MoO3F3, and the V5+ cation toward the edge of the cis-oxide positions for Ag 3VO2F4. Local ordering of oxide and fluoride ligands is observed for both structures.

Original languageEnglish
Pages (from-to)4868-4873
Number of pages6
JournalCrystal Growth and Design
Volume10
Issue number11
DOIs
Publication statusPublished - Nov 3 2010

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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    Chamberlain, J. M., Albrecht, T. A., Lesage, J., Sauvage, F., Stern, C. L., & Poeppelmeier, K. R. (2010). Crystal growth of Ag3 M OxF6-x (M = V, x = 2; M = Mo, x = 3). Crystal Growth and Design, 10(11), 4868-4873. https://doi.org/10.1021/cg100890e