Abstract
Slow cooling of a hot acetonitrile solution of tetrathiafulvalene (TTF) and iodine yields a mixture of crystalline products including monoclinic crystals of high iodine content: TTF·I3. A single-crystal X-ray structure analysis has been carried out on these crystals of symmetry P21/n with four molecules per unit cell. The cell parameters are a = 9.411 (2) Å, b = 18.787 (3) Å, c = 7.771 (1) Å, β = 103.2(1)°, and V = 1374 (1) Å3. The structure consists of integrated stacks along the 〈102〉 axis with TTF+ dimers interspersed between pairs of triiodide ions. Consistent with the structural results, single-crystal measurements indicate that this material exhibits high electrical resistivity with σRT <9 × 10-9 Ω-1 cm-1.
| Original language | English |
|---|---|
| Pages (from-to) | 2986-2989 |
| Number of pages | 4 |
| Journal | Journal of the American Chemical Society |
| Volume | 102 |
| Issue number | 9 |
| Publication status | Published - 1980 |
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Cite this
Crystal structure and properties of tetrathiafulvalenium triiodide. / Teitelbaum, Robert C.; Marks, Tobin J; Johnson, Carroll K.
In: Journal of the American Chemical Society, Vol. 102, No. 9, 1980, p. 2986-2989.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Crystal structure and properties of tetrathiafulvalenium triiodide
AU - Teitelbaum, Robert C.
AU - Marks, Tobin J
AU - Johnson, Carroll K.
PY - 1980
Y1 - 1980
N2 - Slow cooling of a hot acetonitrile solution of tetrathiafulvalene (TTF) and iodine yields a mixture of crystalline products including monoclinic crystals of high iodine content: TTF·I3. A single-crystal X-ray structure analysis has been carried out on these crystals of symmetry P21/n with four molecules per unit cell. The cell parameters are a = 9.411 (2) Å, b = 18.787 (3) Å, c = 7.771 (1) Å, β = 103.2(1)°, and V = 1374 (1) Å3. The structure consists of integrated stacks along the 〈102〉 axis with TTF+ dimers interspersed between pairs of triiodide ions. Consistent with the structural results, single-crystal measurements indicate that this material exhibits high electrical resistivity with σRT <9 × 10-9 Ω-1 cm-1.
AB - Slow cooling of a hot acetonitrile solution of tetrathiafulvalene (TTF) and iodine yields a mixture of crystalline products including monoclinic crystals of high iodine content: TTF·I3. A single-crystal X-ray structure analysis has been carried out on these crystals of symmetry P21/n with four molecules per unit cell. The cell parameters are a = 9.411 (2) Å, b = 18.787 (3) Å, c = 7.771 (1) Å, β = 103.2(1)°, and V = 1374 (1) Å3. The structure consists of integrated stacks along the 〈102〉 axis with TTF+ dimers interspersed between pairs of triiodide ions. Consistent with the structural results, single-crystal measurements indicate that this material exhibits high electrical resistivity with σRT <9 × 10-9 Ω-1 cm-1.
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M3 - Article
VL - 102
SP - 2986
EP - 2989
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 9
ER -