Crystal structure of Zn3.77V1.54Mo1.46O12 containing ZnO6 trigonal prisms

Xiandong Wang; Kevin R. Heier; Charlotte L. Stern; Kenneth R. Poeppelmeier

doi:10.1016/S0925-8388(96)02812-5

Crystal structure of Zn_3.77V_1.54Mo_1.46O₁₂ containing ZnO₆ trigonal prisms

Xiandong Wang, Kevin R. Heier, Charlotte L. Stern, Kenneth R. Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Single crystals of Zn_3.77V_1.54Mo_1.46O₁₂ were grown in a ZnO/V₂O₅/MoO₃ melt. The colorless needles were determined to be orthorhombic, space group P2₁2₁2₁ (No. 19), a=5.048 (4) Å, b=10.400 (2) Å, c=17.560 (7) Å, V=921.9(6) Å³, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P2₁2₁2₁ (acentric).

Original language	English
Pages (from-to)	190-194
Number of pages	5
Journal	Journal of Alloys and Compounds
Volume	255
Issue number	1-2
DOIs	https://doi.org/10.1016/S0925-8388(96)02812-5
Publication status	Published - Jun 22 1997

Keywords

Trigonal prism and acentric
ZnVMoO structure

ASJC Scopus subject areas

Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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@article{0058d60d9fef47b98cbe2ff4c355713a,

title = "Crystal structure of Zn3.77V1.54Mo1.46O12 containing ZnO6 trigonal prisms",

abstract = "Single crystals of Zn3.77V1.54Mo1.46O12 were grown in a ZnO/V2O5/MoO3 melt. The colorless needles were determined to be orthorhombic, space group P212121 (No. 19), a=5.048 (4) {\AA}, b=10.400 (2) {\AA}, c=17.560 (7) {\AA}, V=921.9(6) {\AA}3, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P212121 (acentric).",

keywords = "Trigonal prism and acentric, ZnVMoO structure",

author = "Xiandong Wang and Heier, {Kevin R.} and Stern, {Charlotte L.} and Poeppelmeier, {Kenneth R.}",

note = "Funding Information: The authors wish to thank Dr. Larry Cirjak and acknowledge an Extramural Research Award (EMRA) from BP America, the National Science Foundation (NSF) (No. DMR-9412971 ) and the MRC of Northwestern University supported by NSF (No. DMR-9120521 ) for support of this research work.",

year = "1997",

month = jun,

day = "22",

doi = "10.1016/S0925-8388(96)02812-5",

language = "English",

volume = "255",

pages = "190--194",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier BV",

number = "1-2",

}

TY - JOUR

T1 - Crystal structure of Zn3.77V1.54Mo1.46O12 containing ZnO6 trigonal prisms

AU - Wang, Xiandong

AU - Heier, Kevin R.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R.

N1 - Funding Information: The authors wish to thank Dr. Larry Cirjak and acknowledge an Extramural Research Award (EMRA) from BP America, the National Science Foundation (NSF) (No. DMR-9412971 ) and the MRC of Northwestern University supported by NSF (No. DMR-9120521 ) for support of this research work.

PY - 1997/6/22

Y1 - 1997/6/22

N2 - Single crystals of Zn3.77V1.54Mo1.46O12 were grown in a ZnO/V2O5/MoO3 melt. The colorless needles were determined to be orthorhombic, space group P212121 (No. 19), a=5.048 (4) Å, b=10.400 (2) Å, c=17.560 (7) Å, V=921.9(6) Å3, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P212121 (acentric).

AB - Single crystals of Zn3.77V1.54Mo1.46O12 were grown in a ZnO/V2O5/MoO3 melt. The colorless needles were determined to be orthorhombic, space group P212121 (No. 19), a=5.048 (4) Å, b=10.400 (2) Å, c=17.560 (7) Å, V=921.9(6) Å3, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P212121 (acentric).

KW - Trigonal prism and acentric

KW - ZnVMoO structure

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