Crystal structure of Zn3.77V1.54Mo1.46O12 containing ZnO6 trigonal prisms

Xiandong Wang; Kevin R. Heier; Charlotte L. Stern; Kenneth R Poeppelmeier

Crystal structure of Zn_3.77V_1.54Mo_1.46O₁₂ containing ZnO₆ trigonal prisms

Xiandong Wang, Kevin R. Heier, Charlotte L. Stern, Kenneth R Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article

22 Citations (Scopus)

Abstract

Single crystals of Zn_3.77V_1.54Mo_1.46O₁₂ were grown in a ZnO/V₂O₅/MoO₃ melt. The colorless needles were determined to be orthorhombic, space group P2₁2₁2₁ (No. 19), a=5.048 (4) Å, b=10.400 (2) Å, c=17.560 (7) Å, V=921.9(6) Å³, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P2₁2₁2₁ (acentric).

Original language	English
Pages (from-to)	190-194
Number of pages	5
Journal	Journal of Alloys and Compounds
Volume	255
Issue number	1-2
Publication status	Published - Jun 22 1997

Fingerprint

Bond length

Prisms

Needles

Cations

Zinc

Crystal structure

Positive ions

Single crystals

molybdenum trioxide

vanadium pentoxide

Keywords

Trigonal prism and acentric
ZnVMoO structure

ASJC Scopus subject areas

Metals and Alloys

Cite this

Wang, X., Heier, K. R., Stern, C. L., & Poeppelmeier, K. R. (1997). Crystal structure of Zn_3.77V_1.54Mo_1.46O₁₂ containing ZnO₆ trigonal prisms. Journal of Alloys and Compounds, 255(1-2), 190-194.

Crystal structure of Zn_3.77V_1.54Mo_1.46O₁₂ containing ZnO₆ trigonal prisms. / Wang, Xiandong; Heier, Kevin R.; Stern, Charlotte L.; Poeppelmeier, Kenneth R.

In: Journal of Alloys and Compounds, Vol. 255, No. 1-2, 22.06.1997, p. 190-194.

Research output: Contribution to journal › Article

Wang, X, Heier, KR, Stern, CL & Poeppelmeier, KR 1997, 'Crystal structure of Zn_3.77V_1.54Mo_1.46O₁₂ containing ZnO₆ trigonal prisms', Journal of Alloys and Compounds, vol. 255, no. 1-2, pp. 190-194.

Wang X, Heier KR, Stern CL, Poeppelmeier KR. Crystal structure of Zn_3.77V_1.54Mo_1.46O₁₂ containing ZnO₆ trigonal prisms. Journal of Alloys and Compounds. 1997 Jun 22;255(1-2):190-194.

Wang, Xiandong ; Heier, Kevin R. ; Stern, Charlotte L. ; Poeppelmeier, Kenneth R. / Crystal structure of Zn_3.77V_1.54Mo_1.46O₁₂ containing ZnO₆ trigonal prisms. In: Journal of Alloys and Compounds. 1997 ; Vol. 255, No. 1-2. pp. 190-194.

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abstract = "Single crystals of Zn3.77V1.54Mo1.46O12 were grown in a ZnO/V2O5/MoO3 melt. The colorless needles were determined to be orthorhombic, space group P212121 (No. 19), a=5.048 (4) {\AA}, b=10.400 (2) {\AA}, c=17.560 (7) {\AA}, V=921.9(6) {\AA}3, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P212121 (acentric).",

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