TY - JOUR
T1 - Crystal structure of Zn3.77V1.54Mo1.46O12 containing ZnO6 trigonal prisms
AU - Wang, Xiandong
AU - Heier, Kevin R.
AU - Stern, Charlotte L.
AU - Poeppelmeier, Kenneth R
PY - 1997/6/22
Y1 - 1997/6/22
N2 - Single crystals of Zn3.77V1.54Mo1.46O12 were grown in a ZnO/V2O5/MoO3 melt. The colorless needles were determined to be orthorhombic, space group P212121 (No. 19), a=5.048 (4) Å, b=10.400 (2) Å, c=17.560 (7) Å, V=921.9(6) Å3, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P212121 (acentric).
AB - Single crystals of Zn3.77V1.54Mo1.46O12 were grown in a ZnO/V2O5/MoO3 melt. The colorless needles were determined to be orthorhombic, space group P212121 (No. 19), a=5.048 (4) Å, b=10.400 (2) Å, c=17.560 (7) Å, V=921.9(6) Å3, and Z=4. One type of zinc cation in the structure exhibits trigonal prismatic coordination, and relatively large distortions of the Zn-O bond lengths in the trigonal prisms reduce the symmetry from Pnma (centrosymmetric) to P212121 (acentric).
KW - Trigonal prism and acentric
KW - ZnVMoO structure
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M3 - Article
AN - SCOPUS:0031167664
VL - 255
SP - 190
EP - 194
JO - Journal of Alloys and Compounds
JF - Journal of Alloys and Compounds
SN - 0925-8388
IS - 1-2
ER -