Crystal to crystal guest exchange in a mixed ligand metal-organic framework

Andrew P. Nelson, Damon A. Parrish, Lee R. Cambrea, Lawrence C. Baldwin, Nirupam J. Trivedi, Karen L. Mulfort, Omar K. Farha, Joseph T Hupp

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

The occluded solvent in a mixed ligand metal-organic framework has been displaced by n-hexanol, chloroform, and nitrobenzene in a crystal to crystal guest exchange. The X-ray structures of the three new solvent adducts of Zn 2NDC2DPNI2 reveal the complete replacement of N' ,N-dimethylformamide with the new guest. Structural changes to the framework geometry in response to the size of the incoming guest are also exhibited. These new frameworks are characterized by powder X-ray diffraction, thermal gravimetric analysis coupled with infrared spectroscopy, and cross-polarization magic angle spinning NMR.

Original languageEnglish
Pages (from-to)4588-4591
Number of pages4
JournalCrystal Growth and Design
Volume9
Issue number11
DOIs
Publication statusPublished - Nov 4 2009

Fingerprint

Metals
Ligands
Dimethylformamide
Crystals
ligands
Magic angle spinning
Nitrobenzene
Gravimetric analysis
nitrobenzenes
cross polarization
Chloroform
Chlorine compounds
chloroform
metals
X ray powder diffraction
metal spinning
adducts
crystals
Infrared spectroscopy
thermal analysis

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Nelson, A. P., Parrish, D. A., Cambrea, L. R., Baldwin, L. C., Trivedi, N. J., Mulfort, K. L., ... Hupp, J. T. (2009). Crystal to crystal guest exchange in a mixed ligand metal-organic framework. Crystal Growth and Design, 9(11), 4588-4591. https://doi.org/10.1021/cg900735n

Crystal to crystal guest exchange in a mixed ligand metal-organic framework. / Nelson, Andrew P.; Parrish, Damon A.; Cambrea, Lee R.; Baldwin, Lawrence C.; Trivedi, Nirupam J.; Mulfort, Karen L.; Farha, Omar K.; Hupp, Joseph T.

In: Crystal Growth and Design, Vol. 9, No. 11, 04.11.2009, p. 4588-4591.

Research output: Contribution to journalArticle

Nelson, AP, Parrish, DA, Cambrea, LR, Baldwin, LC, Trivedi, NJ, Mulfort, KL, Farha, OK & Hupp, JT 2009, 'Crystal to crystal guest exchange in a mixed ligand metal-organic framework', Crystal Growth and Design, vol. 9, no. 11, pp. 4588-4591. https://doi.org/10.1021/cg900735n
Nelson AP, Parrish DA, Cambrea LR, Baldwin LC, Trivedi NJ, Mulfort KL et al. Crystal to crystal guest exchange in a mixed ligand metal-organic framework. Crystal Growth and Design. 2009 Nov 4;9(11):4588-4591. https://doi.org/10.1021/cg900735n
Nelson, Andrew P. ; Parrish, Damon A. ; Cambrea, Lee R. ; Baldwin, Lawrence C. ; Trivedi, Nirupam J. ; Mulfort, Karen L. ; Farha, Omar K. ; Hupp, Joseph T. / Crystal to crystal guest exchange in a mixed ligand metal-organic framework. In: Crystal Growth and Design. 2009 ; Vol. 9, No. 11. pp. 4588-4591.
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