Crystalline nickel, cobalt, and manganese antimonates as electrocatalysts for the chlorine evolution reaction

Ivan A. Moreno-Hernandez, Bruce S. Brunschwig, Nathan S. Lewis

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4 Citations (Scopus)

Abstract

The chlorine-evolution reaction (CER) is a common, commercially valuable electrochemical reaction, and is practiced at industrial scale globally. A precious metal solid solution of RuO2 or IrO2 with TiO2 is the predominant electrocatalyst for the CER. Herein we report that materials comprised only of non-precious metal elements, specifically crystalline transition-metal antimonates (TMAs) such as NiSb2Ox, CoSb2Ox, and MnSb2Ox, are moderately active, stable catalysts for the electrochemical oxidation of chloride to chlorine under conditions relevant to the commercial chlor-alkali process. Specifically, CoSb2Ox exhibited a galvanostatic potential of 1.804 V vs. NHE at 100 mA cm-2 of Cl2(g) production from aqueous pH = 2.0, 4.0 M NaCl after 250 h of operation. Studies of the bulk and surface of the electrocatalyst and the composition of the electrolyte before and after electrolysis indicated minimal changes in the surface structure and intrinsic activity of CoSb2Ox as a result of Cl2(g) evolution under these conditions.

Original languageEnglish
Pages (from-to)1241-1248
Number of pages8
JournalEnergy and Environmental Science
Volume12
Issue number4
DOIs
Publication statusPublished - Apr 2019

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ASJC Scopus subject areas

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution

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