Crystallization and structure of a binuclear species containing the Co-C(OH)-O-Co moiety

Etsuko Fujita, David J. Szalda

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

A binuclear species containing the Co-C(OH)-O-Co moiety, [(CoL)2(COOH)](ClO4)3(NCCH3)2 (L = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) was isolated from a CO2 saturated acetonitrile/diethyl ether solution of [CoL(CO2)](ClO4) and its structure was determined. The complex consists of two [CoL]+ units connected by a bridging COOH+ in which the carbon is coordinated to one CoL+ and the non-protonated oxygen to the other CoL+ unit. (C) 2000 Elsevier Science S.A.

Original languageEnglish
Pages (from-to)139-144
Number of pages6
JournalInorganica Chimica Acta
Volume297
Issue number1-2
DOIs
Publication statusPublished - Jan 1 2000

Keywords

  • Cobalt complexes
  • Crystal structures
  • Hydroxycarbonyl complexes
  • Macrocycle complexes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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