Cs2B4SiO9: A deep-ultraviolet nonlinear optical crystal

Hongping Wu; Hongwei Yu; Shilie Pan; Zhenjun Huang; Zhihua Yang; Xin Su; Kenneth R. Poeppelmeier

doi:10.1002/anie.201209151

Cs₂B₄SiO₉: A deep-ultraviolet nonlinear optical crystal

Hongping Wu, Hongwei Yu, Shilie Pan, Zhenjun Huang, Zhihua Yang, Xin Su, Kenneth R. Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article › peer-review

191 Citations (Scopus)

Abstract

Nonlinear optics: A new borosilicate, Cs₂B₄SiO ₉, has been synthesized (see picture). This compound represents a new kind of a boron-rich borosilicate and shows a 4.6 times stronger powder second-harmonic generation response relative to KH₂PO₄. In addition, Cs₂B₄SiO₉ has a short UV cutoff edge (below 190 nm).

Original language	English
Pages (from-to)	3406-3410
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	12
DOIs	https://doi.org/10.1002/anie.201209151
Publication status	Published - Mar 18 2013

Keywords

borates
nonlinear optics
solid-state structures
structure-property relationships

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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AU - Su, Xin

AU - Poeppelmeier, Kenneth R.

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KW - solid-state structures

KW - structure-property relationships

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