Abstract
The reaction of Cu with a molten mixture of Cs2S/P2S5 produced the quaternary compound Cs2CuP3S9. The bright yellow crystals of Cs2CuP3S9 are stable in air and water for several weeks. The compound crystallizes in the chiral, hexagonal space group P65 (No. 170) and at 23°C: a = 15.874(2) Å; c = 35.100(7) Å; V = 7660(3) Å3; Z = 18. The [CuP3S9](n)/(2n-) chains are composed of an alternating arrangement of tetrahedral Cu+ ions and cyclic [P3S9]3- units. The structure contains parallel helical [CuP3S9](n)/(2n-) chains that run along the c-axis. The cyclic [P3S9]3- unit derives from the molecular adamantane [P4S10] unit with one [PS]3+ vertex removed. The title compound was characterized by differential thermal analysis, far-IR, Raman, and single-crystal optical transmission UV/vis spectroscopy. Positive nonlinear optical response and second harmonic generation response was observed. (C) 2000 Academic Press.
| Original language | English |
|---|---|
| Pages (from-to) | 326-329 |
| Number of pages | 4 |
| Journal | Journal of Solid State Chemistry |
| Volume | 151 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 2000 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Cs2CuP3S9 : A chiral compound with screw helices. / Hanko, Jason A.; Kanatzidis, Mercouri G.
In: Journal of Solid State Chemistry, Vol. 151, No. 2, 2000, p. 326-329.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Cs2CuP3S9
T2 - A chiral compound with screw helices
AU - Hanko, Jason A.
AU - Kanatzidis, Mercouri G
PY - 2000
Y1 - 2000
N2 - The reaction of Cu with a molten mixture of Cs2S/P2S5 produced the quaternary compound Cs2CuP3S9. The bright yellow crystals of Cs2CuP3S9 are stable in air and water for several weeks. The compound crystallizes in the chiral, hexagonal space group P65 (No. 170) and at 23°C: a = 15.874(2) Å; c = 35.100(7) Å; V = 7660(3) Å3; Z = 18. The [CuP3S9](n)/(2n-) chains are composed of an alternating arrangement of tetrahedral Cu+ ions and cyclic [P3S9]3- units. The structure contains parallel helical [CuP3S9](n)/(2n-) chains that run along the c-axis. The cyclic [P3S9]3- unit derives from the molecular adamantane [P4S10] unit with one [PS]3+ vertex removed. The title compound was characterized by differential thermal analysis, far-IR, Raman, and single-crystal optical transmission UV/vis spectroscopy. Positive nonlinear optical response and second harmonic generation response was observed. (C) 2000 Academic Press.
AB - The reaction of Cu with a molten mixture of Cs2S/P2S5 produced the quaternary compound Cs2CuP3S9. The bright yellow crystals of Cs2CuP3S9 are stable in air and water for several weeks. The compound crystallizes in the chiral, hexagonal space group P65 (No. 170) and at 23°C: a = 15.874(2) Å; c = 35.100(7) Å; V = 7660(3) Å3; Z = 18. The [CuP3S9](n)/(2n-) chains are composed of an alternating arrangement of tetrahedral Cu+ ions and cyclic [P3S9]3- units. The structure contains parallel helical [CuP3S9](n)/(2n-) chains that run along the c-axis. The cyclic [P3S9]3- unit derives from the molecular adamantane [P4S10] unit with one [PS]3+ vertex removed. The title compound was characterized by differential thermal analysis, far-IR, Raman, and single-crystal optical transmission UV/vis spectroscopy. Positive nonlinear optical response and second harmonic generation response was observed. (C) 2000 Academic Press.
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UR - http://www.scopus.com/inward/citedby.url?scp=0033673701&partnerID=8YFLogxK
U2 - 10.1006/jssc.2000.8709
DO - 10.1006/jssc.2000.8709
M3 - Article
VL - 151
SP - 326
EP - 329
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 2
ER -