Cs2PbI2Cl2, All-Inorganic Two-Dimensional Ruddlesden-Popper Mixed Halide Perovskite with Optoelectronic Response

Jiangwei Li, Qin Yu, Yihui He, Constantinos C. Stoumpos, Guangda Niu, Giancarlo G. Trimarchi, Hang Guo, Guifang Dong, Dong Wang, Liduo Wang, Mercouri G. Kanatzidis

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Abstract

The two-dimensional Ruddlesden-Popper (RP) phases are an important class of halide perovskites with versatile optoelectronic properties. So far, only organic-inorganic hybrid RP phases involving long organic spacers were reported in this class. Here, we report an all-inorganic RP phase lead halide perovskite, Cs2PbI2Cl2 (1, I4/mmm space group; a = 5.6385(8) Å, c = 18.879(4) Å), synthesized by a solid-state method. The compound exhibits a band gap of Eg â 3.04 eV and photoconductivity. We find an anomalous band gap evolution in Cs2Pb1-xSnxI2Cl2 solid solutions. Our combined density functional theory and experimental study supports the thermodynamically stable nature of 1 as a unique ordered phase in the Cs2PbX4 (X = Cl, Br, I) system. The calculations suggest that 1 is a direct bandgap semiconductor with relatively small effective carrier mass along the in-plane direction, consistent with the experimentally observed in-plane UV-light photoresponse. We also demonstrate that 1 is promising for radiation detection capable of α-particle counting. Moreover, 1 shows markedly ambient and thermal stability.

Original languageEnglish
Pages (from-to)11085-11090
Number of pages6
JournalJournal of the American Chemical Society
Volume140
Issue number35
DOIs
Publication statusPublished - Sep 5 2018

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ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Li, J., Yu, Q., He, Y., Stoumpos, C. C., Niu, G., Trimarchi, G. G., Guo, H., Dong, G., Wang, D., Wang, L., & Kanatzidis, M. G. (2018). Cs2PbI2Cl2, All-Inorganic Two-Dimensional Ruddlesden-Popper Mixed Halide Perovskite with Optoelectronic Response. Journal of the American Chemical Society, 140(35), 11085-11090. https://doi.org/10.1021/jacs.8b06046