Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Andrea N. Alsobrook; Brad G. Hauser; Joseph T. Hupp; Evgeny V. Alekseev; Wulf Depmeier; Thomas E. Albrecht-Schmitt

doi:10.1039/c0cc03507f

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Andrea N. Alsobrook, Brad G. Hauser, Joseph T. Hupp, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht-Schmitt

Northwestern University

Research output: Contribution to journal › Article

95 Citations (Scopus)

Abstract

Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M₂[(UO₂)₆(PO ₃CH₂CO₂)₃O₃(OH)(H ₂O)₂]·16H₂O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd₃(UO₂)₆(PO₃CH ₂CO₂)₆(H₂O)₁₃] ·6H₂O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO₂ uptake of 40 m² g^-1 at 273 K, and no uptake of N₂ at 77 K.

Original language	English
Pages (from-to)	9167-9169
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	48
DOIs	https://doi.org/10.1039/c0cc03507f
Publication status	Published - Dec 28 2010

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Alsobrook, A. N., Hauser, B. G., Hupp, J. T., Alekseev, E. V., Depmeier, W., & Albrecht-Schmitt, T. E. (2010). Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials. Chemical Communications, 46(48), 9167-9169. https://doi.org/10.1039/c0cc03507f

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate : New methods for constructing porous materials. / Alsobrook, Andrea N.; Hauser, Brad G.; Hupp, Joseph T.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E.

In: Chemical Communications, Vol. 46, No. 48, 28.12.2010, p. 9167-9169.

Research output: Contribution to journal › Article

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abstract = "Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.",

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10.1039/c0cc03507f