Abstract
Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.
| Original language | English |
|---|---|
| Pages (from-to) | 9167-9169 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 46 |
| Issue number | 48 |
| DOIs | |
| Publication status | Published - Dec 28 2010 |
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ASJC Scopus subject areas
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Catalysis
- Chemistry(all)
Cite this
Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate : New methods for constructing porous materials. / Alsobrook, Andrea N.; Hauser, Brad G.; Hupp, Joseph T; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E.
In: Chemical Communications, Vol. 46, No. 48, 28.12.2010, p. 9167-9169.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate
T2 - New methods for constructing porous materials
AU - Alsobrook, Andrea N.
AU - Hauser, Brad G.
AU - Hupp, Joseph T
AU - Alekseev, Evgeny V.
AU - Depmeier, Wulf
AU - Albrecht-Schmitt, Thomas E.
PY - 2010/12/28
Y1 - 2010/12/28
N2 - Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.
AB - Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.
UR - http://www.scopus.com/inward/record.url?scp=78649678126&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=78649678126&partnerID=8YFLogxK
U2 - 10.1039/c0cc03507f
DO - 10.1039/c0cc03507f
M3 - Article
VL - 46
SP - 9167
EP - 9169
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 48
ER -