Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Andrea N. Alsobrook; Brad G. Hauser; Joseph T. Hupp; Evgeny V. Alekseev; Wulf Depmeier; Thomas E. Albrecht-Schmitt

doi:10.1039/c0cc03507f

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Andrea N. Alsobrook, Brad G. Hauser, Joseph T. Hupp, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht-Schmitt

Northwestern University

Research output: Contribution to journal › Article › peer-review

98 Citations (Scopus)

Abstract

Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M₂[(UO₂)₆(PO ₃CH₂CO₂)₃O₃(OH)(H ₂O)₂]·16H₂O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd₃(UO₂)₆(PO₃CH ₂CO₂)₆(H₂O)₁₃] ·6H₂O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO₂ uptake of 40 m² g^-1 at 273 K, and no uptake of N₂ at 77 K.

Original language	English
Pages (from-to)	9167-9169
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	48
DOIs	https://doi.org/10.1039/c0cc03507f
Publication status	Published - Dec 28 2010

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate : New methods for constructing porous materials. / Alsobrook, Andrea N.; Hauser, Brad G.; Hupp, Joseph T.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E.

In: Chemical Communications, Vol. 46, No. 48, 28.12.2010, p. 9167-9169.

Research output: Contribution to journal › Article › peer-review

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abstract = "Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.",

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AU - Alekseev, Evgeny V.

AU - Depmeier, Wulf

AU - Albrecht-Schmitt, Thomas E.

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N2 - Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.

AB - Four heterobimetallic U(vi)/M(ii) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO 3CH2CO2)3O3(OH)(H 2O)2]·16H2O (M = Mn(ii), Co(ii), and Cd(ii)) adopt cubic three-dimensional network structures with large cavities approximately 16 in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH 2CO2)6(H2O)13] ·6H2O forms a rhombohedral channel structure with hydrated Cd(ii) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g-1 at 273 K, and no uptake of N2 at 77 K.

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Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: New methods for constructing porous materials

Abstract

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